About: Crystal Structure of [Zn(2-Bromobenzoato)(2)](n) and [Zn(2-Bromobenzoato)(2)(N-Methylnicotinamide)](2)

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About: Crystal Structure of [Zn(2-Bromobenzoato)(2)](n) and [Zn(2-Bromobenzoato)(2)(N-Methylnicotinamide)](2) Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The syntheses and structural characterizations of two novel 2-bromobenzoatozinc(II) complexes-[Zn(2-BrC6H4COO)(2)](n) (I) and [Zn(2-BrC6H4COO)(2)(mnad)](2) (II), where mnad is N-methylnicotinamide are reported. Compound (I) crystallized with a monoclinic lattice (space group P2(1)/c) and is polymeric in solid state. Its cell parameters are: a = 7.37220(10) angstrom, b = 19.9639(3) angstrom, c = 30.2756(5) angstrom, beta = 94.7510(7)degrees, V = 4440.59(12) angstrom(3), Z = 4. The coordination environments of all zinc atoms are distorted tetrahedra built from four carboxylate oxygen atoms coming from four 2-bromobenzoato ligands. Compound (II) crystallized with a monoclinic lattice (space group P2(1)/c) with a = 11.7488(2) angstrom, b = 20.3683(3) angstrom, c = 9.30130(10) angstrom, beta = 100.3941(11)degrees, V = 2189.30(5) angstrom(3), Z = 2. This dimeric molecule features a paddle-wheel [Zn2O8] cage in solid state; the coordination environment of the central atom is square pyramidal consisting of four carboxylate oxygen atoms and the pyridine N atom of the mnad ligand. The syntheses and structural characterizations of two novel 2-bromobenzoatozinc(II) complexes-[Zn(2-BrC6H4COO)(2)](n) (I) and [Zn(2-BrC6H4COO)(2)(mnad)](2) (II), where mnad is N-methylnicotinamide are reported. Compound (I) crystallized with a monoclinic lattice (space group P2(1)/c) and is polymeric in solid state. Its cell parameters are: a = 7.37220(10) angstrom, b = 19.9639(3) angstrom, c = 30.2756(5) angstrom, beta = 94.7510(7)degrees, V = 4440.59(12) angstrom(3), Z = 4. The coordination environments of all zinc atoms are distorted tetrahedra built from four carboxylate oxygen atoms coming from four 2-bromobenzoato ligands. Compound (II) crystallized with a monoclinic lattice (space group P2(1)/c) with a = 11.7488(2) angstrom, b = 20.3683(3) angstrom, c = 9.30130(10) angstrom, beta = 100.3941(11)degrees, V = 2189.30(5) angstrom(3), Z = 2. This dimeric molecule features a paddle-wheel [Zn2O8] cage in solid state; the coordination environment of the central atom is square pyramidal consisting of four carboxylate oxygen atoms and the pyridine N atom of the mnad ligand. (en)
Title	Crystal Structure of [Zn(2-Bromobenzoato)(2)](n) and [Zn(2-Bromobenzoato)(2)(N-Methylnicotinamide)](2) Crystal Structure of [Zn(2-Bromobenzoato)(2)](n) and [Zn(2-Bromobenzoato)(2)(N-Methylnicotinamide)](2) (en)
skos:prefLabel	Crystal Structure of [Zn(2-Bromobenzoato)(2)](n) and [Zn(2-Bromobenzoato)(2)(N-Methylnicotinamide)](2) Crystal Structure of [Zn(2-Bromobenzoato)(2)](n) and [Zn(2-Bromobenzoato)(2)(N-Methylnicotinamide)](2) (en)
skos:notation	RIV/61388955:_____/10:00437045!RIV15-AV0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(KAN100400701), Z(AV0Z40400503), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	8
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Gyepes, Robert
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	252446
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/10:00437045
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	N-methylnicotinamide; Structural study; Zinc 2-bromobenzoate (en)
http://linked.open.../riv/klicoveSlovo	N-methylnicotinamide Structural study Zinc 2-bromobenzoate
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[5D9FB68DB4D3]
http://linked.open...i/riv/nazevZdroje	Journal of Chemical Crystallography
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Hybride nanocomposite materials
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	40
http://linked.open...iv/tvurceVysledku	Gyepes, Robert Krajniková, A. Györová, K.
http://linked.open...ain/vavai/riv/wos	000279197600003
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	1074-1542
number of pages	6 (xsd:int)
http://bibframe.org/vocab/doi	10.1007/s10870-010-9712-z

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