About: Time-resolved Fourier-transform infrared emission spectroscopy of Au in the 1800-4000-cm(-1) region: Rydberg transitions

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About: Time-resolved Fourier-transform infrared emission spectroscopy of Au in the 1800-4000-cm(-1) region: Rydberg transitions Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Time-resolved Fourier-transform infrared spectroscopy was applied for observations of the emission arising after irradiation of a Au target with a pulsed nanosecond ArF (lambda = 193 nm) laser. A high-repetition-rate laser (1.0 kHz) with an output energy of 15 mJ was focused on a rotating metal target inside a vacuum chamber (average pressure 10(-2) Torr). The infrared emission spectra were observed in the 1800-4000 cm(-1) spectral region with a time profile showing maximum emission intensity in 9 -11 mu s after a laser shot. Seven prominent lines are reported; most of them are identified as being due to transitions between low Rydberg nl states of Au with n = 5-10 and l = 0-3. An alternative identification (6f(5/2) -> 7d(3/2)) is given for the 2518.489 cm(-1) line previously classified as 8d(5/2) -> 5f(5/2). On the basis of the measured lines, three f levels of the Au atom are reported and revised values are given for six other levels. Time-resolved Fourier-transform infrared spectroscopy was applied for observations of the emission arising after irradiation of a Au target with a pulsed nanosecond ArF (lambda = 193 nm) laser. A high-repetition-rate laser (1.0 kHz) with an output energy of 15 mJ was focused on a rotating metal target inside a vacuum chamber (average pressure 10(-2) Torr). The infrared emission spectra were observed in the 1800-4000 cm(-1) spectral region with a time profile showing maximum emission intensity in 9 -11 mu s after a laser shot. Seven prominent lines are reported; most of them are identified as being due to transitions between low Rydberg nl states of Au with n = 5-10 and l = 0-3. An alternative identification (6f(5/2) -> 7d(3/2)) is given for the 2518.489 cm(-1) line previously classified as 8d(5/2) -> 5f(5/2). On the basis of the measured lines, three f levels of the Au atom are reported and revised values are given for six other levels. (en)
Title	Time-resolved Fourier-transform infrared emission spectroscopy of Au in the 1800-4000-cm(-1) region: Rydberg transitions Time-resolved Fourier-transform infrared emission spectroscopy of Au in the 1800-4000-cm(-1) region: Rydberg transitions (en)
skos:prefLabel	Time-resolved Fourier-transform infrared emission spectroscopy of Au in the 1800-4000-cm(-1) region: Rydberg transitions Time-resolved Fourier-transform infrared emission spectroscopy of Au in the 1800-4000-cm(-1) region: Rydberg transitions (en)
skos:notation	RIV/61388955:_____/10:00347582!RIV11-AV0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(IAA400400705), P(KAN100500652), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Civiš, Svatopluk Matulková, Irena Cihelka, Jaroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	292934
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/10:00347582
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	spectroscopy; Rydberg transitions; theoretical chemistry (en)
http://linked.open.../riv/klicoveSlovo	Rydberg transitions spectroscopy theoretical chemistry
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[012D35F6FBFF]
http://linked.open...i/riv/nazevZdroje	Physical Review. A
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Fourier transform semiconductor laser spectroscopy Heterogeneous and hybrid nanocomposite materials for solar cells
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	81
http://linked.open...iv/tvurceVysledku	Civiš, Svatopluk Matulková, Irena Cihelka, Jaroslav
http://linked.open...ain/vavai/riv/wos	000277958100016
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	1050-2947
number of pages	7 (xsd:int)

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