About: Selective Monoacylation of Ferrocene with Bulky Acylating Agents over Mesoporous Sieve AlKIT-5

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Ferrocene acylation with bulky acylating agents (1-adamantoyl, benzoyl, 2-chlorobenzoyl, and cinnamoyl chlorides; and benzoic anhydride) catalyzed by AlKIT-5 mesoporous catalysts was investigated. AlKIT-5 catalysts with varying ratios of Si/Al were synthesized using tetraethoxysilane and aluminum isopropoxide as the structural building blocks and Pluronic F127 as a template under acidic conditions and were characterized in detail by X-ray powder diffraction, magic-angle spinning (MAS) NMR spectroscopy, sorption of nitrogen, energy-dispersive X-ray spectroscopy (EDS), SEM, TEM, and FTIR with pyridine as a probe molecule. The catalytic activity of the prepared AlKIT-5 catalysts in ferrocene acylation was shown to depend on the type of the acylating agent, thus likely reflecting the strength of interactions between the acyl source, the product, and the solid catalysts when the acylation reaction was carried out at 100 °C. Ferrocene acylation with bulky acylating agents (1-adamantoyl, benzoyl, 2-chlorobenzoyl, and cinnamoyl chlorides; and benzoic anhydride) catalyzed by AlKIT-5 mesoporous catalysts was investigated. AlKIT-5 catalysts with varying ratios of Si/Al were synthesized using tetraethoxysilane and aluminum isopropoxide as the structural building blocks and Pluronic F127 as a template under acidic conditions and were characterized in detail by X-ray powder diffraction, magic-angle spinning (MAS) NMR spectroscopy, sorption of nitrogen, energy-dispersive X-ray spectroscopy (EDS), SEM, TEM, and FTIR with pyridine as a probe molecule. The catalytic activity of the prepared AlKIT-5 catalysts in ferrocene acylation was shown to depend on the type of the acylating agent, thus likely reflecting the strength of interactions between the acyl source, the product, and the solid catalysts when the acylation reaction was carried out at 100 °C. (en)
Title	Selective Monoacylation of Ferrocene with Bulky Acylating Agents over Mesoporous Sieve AlKIT-5 Selective Monoacylation of Ferrocene with Bulky Acylating Agents over Mesoporous Sieve AlKIT-5 (en)
skos:prefLabel	Selective Monoacylation of Ferrocene with Bulky Acylating Agents over Mesoporous Sieve AlKIT-5 Selective Monoacylation of Ferrocene with Bulky Acylating Agents over Mesoporous Sieve AlKIT-5 (en)
skos:notation	RIV/61388955:_____/10:00345802!RIV11-GA0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA104/07/0383), P(GD203/08/H032), Z(AV0Z40400503), Z(MSM0021620857)
http://linked.open...iv/cisloPeriodika	26
http://linked.open...vai/riv/dodaniDat	2011
http://linked.open...aciTvurceVysledku	Vlk, Josef Bejblová, Martina Procházková, Dana Čejka, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	286803
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/10:00345802
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	acylation; aluminum; ferrocene (en)
http://linked.open.../riv/klicoveSlovo	acylation aluminum ferrocene
http://linked.open...odStatuVydavatele	DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV	[80B8929CAF47]
http://linked.open...i/riv/nazevZdroje	Chemistry - A European Journal
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Development of new heterogeneous catalysts for acylation reactions Advanced catalytic processes and materials
http://linked.open...UplatneniVysledku	2010
http://linked.open...v/svazekPeriodika	16
http://linked.open...iv/tvurceVysledku	Procházková, Dana Vlk, Josef Čejka, Jiří Štěpnička, P. Vinu, A. Voláková, Martina
http://linked.open...ain/vavai/riv/wos	000280431900018
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Nové molekulární systémy pro pokročilé aplikace prospěšné pro zdraví a šetrné k životnímu prostředí
issn	0947-6539
number of pages	8 (xsd:int)

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