About: 1-Zircona-2,5-disilacyclopent-3-in: ein Zirconocen-koordiniertes 1,4-Disilabutatrien?     Goto   Sponge   NotDistinct   Permalink

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Description
  • Alkyne under stress: A novel metallacycle containing one Zr atom, two Si atoms, and a C=C bond has been prepared and its structure elucidated (Zr green, Si blue, C gray). According to X-ray data, spectral properties, and DFT calculations, the bonding situation in this compound is characterized as a 1-metalla-2,5-disilacyclopent-3-yne with a weak metal-triple-bond interaction. (en)
  • Ein Alkin unter Stress: Ein neuartiger Metallacyclus mit einem Zr- und zwei Si-Atomen sowie einer C-C-Dreifachbindung wurde hergestellt und seine Molekülstruktur bestimmt (siehe Bild; Zr grün, Si blau, C grau). Nach den spektroskopischen und den Strukturdaten sowie DFT-Rechnungen ist diese Verbindung ein 1-Metalla-2,5-disilacyclopent-3-in mit schwacher Wechselwirkung zwischen Metallzentrum und Dreifachbindung.
Title
  • 1-Zircona-2,5-disilacyclopent-3-in: ein Zirconocen-koordiniertes 1,4-Disilabutatrien?
  • Formation of a 1-Zircona-2,5-disilacyclopent-3-yne: Coordination of 1,4-Disilabutatriene to Zirconocene? (en)
skos:prefLabel
  • 1-Zircona-2,5-disilacyclopent-3-in: ein Zirconocen-koordiniertes 1,4-Disilabutatrien?
  • Formation of a 1-Zircona-2,5-disilacyclopent-3-yne: Coordination of 1,4-Disilabutatriene to Zirconocene? (en)
skos:notation
  • RIV/61388955:_____/10:00342618!RIV11-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 16
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 300767
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/10:00342618
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • 1-Zircona-2,5-disilacyclopent-3-yne; 1,4-Disilabutatriene; zirconocene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [772614DAF1C3]
http://linked.open...i/riv/nazevZdroje
  • Angewandte Chemie
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 122
http://linked.open...iv/tvurceVysledku
  • Lamač, Martin
  • Jiao, H.
  • Spannenberg, A.
  • Hansen, S.
  • Arndt, P.
  • Baumann, W.
  • Rosenthal, U.
http://linked.open...n/vavai/riv/zamer
issn
  • 0570-0833
number of pages
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