About: Proton transfer across a liquid/liquid interface facilitated by phospholipid interfacial films

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The five-step mechanism proposed earlier for the formation of phospholipid films at aqueous/organic interfaces and for their behaviour involving transfer of protons from the aqueous to the organic phase was further studied by cyclic voltammetry. A theoretical model was created for this mechanism and compared with the experimental results. Both the experimental and theoretical results support the proposed mechanism and evaluate the importance of the individual steps. It seems that the decisive step is the regeneration of the zwitterionic form of the phospholipid at the interface, ensuring stability of the film in time and its continuous functioning. In view of the complexity of the system, a wider selection of methods will be needed for a further study of this system; the theoretical model will then gradually be made more sophisticated. The five-step mechanism proposed earlier for the formation of phospholipid films at aqueous/organic interfaces and for their behaviour involving transfer of protons from the aqueous to the organic phase was further studied by cyclic voltammetry. A theoretical model was created for this mechanism and compared with the experimental results. Both the experimental and theoretical results support the proposed mechanism and evaluate the importance of the individual steps. It seems that the decisive step is the regeneration of the zwitterionic form of the phospholipid at the interface, ensuring stability of the film in time and its continuous functioning. In view of the complexity of the system, a wider selection of methods will be needed for a further study of this system; the theoretical model will then gradually be made more sophisticated. (en)
Title	Proton transfer across a liquid/liquid interface facilitated by phospholipid interfacial films Proton transfer across a liquid/liquid interface facilitated by phospholipid interfacial films (en)
skos:prefLabel	Proton transfer across a liquid/liquid interface facilitated by phospholipid interfacial films Proton transfer across a liquid/liquid interface facilitated by phospholipid interfacial films (en)
skos:notation	RIV/61388955:_____/09:00341183!RIV10-MSM-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(LC06063), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	1-2
http://linked.open...vai/riv/dodaniDat	2010
http://linked.open...aciTvurceVysledku	Jänchenová, Hana Mareček, Vladimír Holub, Karel
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	337314
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/09:00341183
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	liquid-liquid interface; proton transfer; phospholipid layers (en)
http://linked.open.../riv/klicoveSlovo	proton transfer liquid-liquid interface phospholipid layers
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[2FD09AFD3601]
http://linked.open...i/riv/nazevZdroje	Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...vavai/riv/projekt	Flurescence microscopy in biological and medical research
http://linked.open...UplatneniVysledku	2009
http://linked.open...v/svazekPeriodika	632
http://linked.open...iv/tvurceVysledku	Mareček, Vladimír Štulík, K. Holub, Karel Jänchenová, Hana
http://linked.open...ain/vavai/riv/wos	000267432300002
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	1572-6657
number of pages	6 (xsd:int)

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