Attributes | Values |
---|
rdf:type
| |
Description
| - A series of compounds [Cp*Ti-2(III)OR'] where R' is (Pr3Si)-Pr-i (2), Ph3Si (3), ((BuO)-Bu-t)(3)Si (4), (c-C5H9)(7)Si8O12 (5), and Bu-t (6) were prepared by protolysis of the titanium-methylene bond in singly tucked-in permethyltitanocene [Cp*Ti(III)(eta(5):eta(1)-C5Me4CH2)] with the respective silanols or tert-butanol. Their electronic transitions from the ground-state molecules to their first excited states (dominantly a 1a(1) -> b(2) transition) occur in the range 1300-1800 nm, originating from pi-donation from oxygen lone pair electrons to the Ti-O bond (as found by Andersen et al. J. Am. Chem. Soc. 1996, 118, 1719).
- A series of compounds [Cp*Ti-2(III)OR'] where R' is (Pr3Si)-Pr-i (2), Ph3Si (3), ((BuO)-Bu-t)(3)Si (4), (c-C5H9)(7)Si8O12 (5), and Bu-t (6) were prepared by protolysis of the titanium-methylene bond in singly tucked-in permethyltitanocene [Cp*Ti(III)(eta(5):eta(1)-C5Me4CH2)] with the respective silanols or tert-butanol. Their electronic transitions from the ground-state molecules to their first excited states (dominantly a 1a(1) -> b(2) transition) occur in the range 1300-1800 nm, originating from pi-donation from oxygen lone pair electrons to the Ti-O bond (as found by Andersen et al. J. Am. Chem. Soc. 1996, 118, 1719). (en)
|
Title
| - Evaluation of the Oxygen pi-Donation in Permethyltitanocene Silanolates and Alcoholates
- Evaluation of the Oxygen pi-Donation in Permethyltitanocene Silanolates and Alcoholates (en)
|
skos:prefLabel
| - Evaluation of the Oxygen pi-Donation in Permethyltitanocene Silanolates and Alcoholates
- Evaluation of the Oxygen pi-Donation in Permethyltitanocene Silanolates and Alcoholates (en)
|
skos:notation
| - RIV/61388955:_____/09:00336713!RIV10-MSM-61388955
|
http://linked.open...avai/riv/aktivita
| |
http://linked.open...avai/riv/aktivity
| - P(KAN100400701), P(LC06070), Z(AV0Z40400503), Z(MSM0021620857)
|
http://linked.open...iv/cisloPeriodika
| |
http://linked.open...vai/riv/dodaniDat
| |
http://linked.open...aciTvurceVysledku
| |
http://linked.open.../riv/druhVysledku
| |
http://linked.open...iv/duvernostUdaju
| |
http://linked.open...titaPredkladatele
| |
http://linked.open...dnocenehoVysledku
| |
http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/09:00336713
|
http://linked.open...riv/jazykVysledku
| |
http://linked.open.../riv/klicovaSlova
| - oxygen; silanolates; alcoholates (en)
|
http://linked.open.../riv/klicoveSlovo
| |
http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
|
http://linked.open...ontrolniKodProRIV
| |
http://linked.open...i/riv/nazevZdroje
| |
http://linked.open...in/vavai/riv/obor
| |
http://linked.open...ichTvurcuVysledku
| |
http://linked.open...cetTvurcuVysledku
| |
http://linked.open...vavai/riv/projekt
| |
http://linked.open...UplatneniVysledku
| |
http://linked.open...v/svazekPeriodika
| |
http://linked.open...iv/tvurceVysledku
| - Mach, Karel
- Gyepes, R.
- Horáček, Michal
- Kubišta, Jiří
- Varga, V.
- Cisařová, I.
|
http://linked.open...ain/vavai/riv/wos
| |
http://linked.open...n/vavai/riv/zamer
| |
issn
| |
number of pages
| |