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  • Photoluminescence of Cr3+ impurity ions was studied on nanocrystalline SrTiO3:Cr(0.1%) powders with an average particle size between 13 and 100 nm. The position of the zero-phonon emission R-line of the octahedral Cr3+ centres shifted to higher energies with decreasing particle size. The temperature shift of the R-line position appeared for all powders nearly the same as the 'dielectric related' one in the bulk crystals, evidencing that SrTiO3 retains quantum paraelectric behaviour down to a particle size of about 10 nm.
  • Photoluminescence of Cr3+ impurity ions was studied on nanocrystalline SrTiO3:Cr(0.1%) powders with an average particle size between 13 and 100 nm. The position of the zero-phonon emission R-line of the octahedral Cr3+ centres shifted to higher energies with decreasing particle size. The temperature shift of the R-line position appeared for all powders nearly the same as the 'dielectric related' one in the bulk crystals, evidencing that SrTiO3 retains quantum paraelectric behaviour down to a particle size of about 10 nm. (en)
Title
  • Luminescent impurity ion probe and low temperature phase of SrTiO3 nanoparticles
  • Luminescent impurity ion probe and low temperature phase of SrTiO3 nanoparticles (en)
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  • Luminescent impurity ion probe and low temperature phase of SrTiO3 nanoparticles
  • Luminescent impurity ion probe and low temperature phase of SrTiO3 nanoparticles (en)
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  • RIV/61388955:_____/09:00336486!RIV10-MSM-61388955
http://linked.open...avai/riv/aktivita
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  • P(1M06002), P(GA202/08/1009), P(KAN301370701), P(KJB100100703), Z(AV0Z10100522), Z(AV0Z40400503), Z(MSM6840770021)
http://linked.open...iv/cisloPeriodika
  • 11
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  • 324248
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  • RIV/61388955:_____/09:00336486
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  • strontium titanate; nanocrystals; impurity ions; optical absorption; zero-phonon line (en)
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  • GB - Spojené království Velké Británie a Severního Irska
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  • [DA2ED51E75F8]
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  • Materials Science and Technology
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  • 25
http://linked.open...iv/tvurceVysledku
  • Dejneka, Alexandr
  • Jastrabík, Lubomír
  • Potůček, Zdeněk
  • Sazama, Petr
  • Trepakov, Vladimír
  • Badalyan, A. G.
  • Makarova, Marina
http://linked.open...ain/vavai/riv/wos
  • 000272049300009
http://linked.open...n/vavai/riv/zamer
issn
  • 0267-0836
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