About: Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide     Goto   Sponge   NotDistinct   Permalink

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  • Novel functionalized adsorbents for CO2 separation were synthesized by grafting 3-aminopropyl, 3-(methylamino)propyl, or 3-(phenylamino)propyl ligands in the delaminated zeolite ITQ-6. On the basis of the texture parameters determined from nitrogen adsorption isotherms recorded at 77 K and the results of chemical analysis, physicochemical properties of functionalized ITQ-6 were evaluated and compared with those of mesoporous SBA-15 silica functionalized with the same ligands. To examine carbon dioxide adsorption on functionalized materials, adsorption isotherms at 293 K were measured. To obtain information on the surface energetics of CO2 adsorption on selected samples, isotherms were taken in the temperature range from 273 to 333 K and adsorption isosteres were calculated. Isosteric adsorption heats determined from the slope of adsorption isosteres proved that all of the 3-aminopropyl ligands in ITQ-6 take part in CO2 adsorption.
  • Novel functionalized adsorbents for CO2 separation were synthesized by grafting 3-aminopropyl, 3-(methylamino)propyl, or 3-(phenylamino)propyl ligands in the delaminated zeolite ITQ-6. On the basis of the texture parameters determined from nitrogen adsorption isotherms recorded at 77 K and the results of chemical analysis, physicochemical properties of functionalized ITQ-6 were evaluated and compared with those of mesoporous SBA-15 silica functionalized with the same ligands. To examine carbon dioxide adsorption on functionalized materials, adsorption isotherms at 293 K were measured. To obtain information on the surface energetics of CO2 adsorption on selected samples, isotherms were taken in the temperature range from 273 to 333 K and adsorption isosteres were calculated. Isosteric adsorption heats determined from the slope of adsorption isosteres proved that all of the 3-aminopropyl ligands in ITQ-6 take part in CO2 adsorption. (en)
Title
  • Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide
  • Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide (en)
skos:prefLabel
  • Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide
  • Functionalization of Delaminated Zeolite ITQ-6 for the Adsorption of Carbon Dioxide (en)
skos:notation
  • RIV/61388955:_____/09:00328669!RIV10-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/08/0604), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 17
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 315726
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/09:00328669
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • zeolites; ITQ-6; carbon dioxide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [43C12065E543]
http://linked.open...i/riv/nazevZdroje
  • Langmuir
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 25
http://linked.open...iv/tvurceVysledku
  • Mayerová, Jana
  • Zukal, Arnošt
  • Čejka, Jiří
  • Pérez-Dominguez, Irene
http://linked.open...ain/vavai/riv/wos
  • 000269197500096
http://linked.open...n/vavai/riv/zamer
issn
  • 0743-7463
number of pages
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