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rdf:type
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Description
| - A series of phosphorescent cyclometalated heteroleptic iridium(III) phenylpyridinato (ppy) complexes containing luminescent 1-Pyridylimidazo [1,5-.alpha.]pyridine (pip) ligands, namely [Ir(ppy)2 (pip)]+, have been synthesized, characterized and their electrochemical, photophysical and electronic properties studied. Seven X-ray structures have been resolved. Excitation of [[Ir(ppy)2 (pip)]+ in acetonitrile solutions at room temperature results in a dual luminescence, strongly quenched by O2. Four complexes show, in absence of O2, a highenergy emission (assigned to a 3MLLCT transition) with two maxima in the blue region of the visible spectra, and a second structured emission (assigned largely to a 3LC .pi.–.pi.* transition). The electrochemical behaviour of all complexes is also reported.
- A series of phosphorescent cyclometalated heteroleptic iridium(III) phenylpyridinato (ppy) complexes containing luminescent 1-Pyridylimidazo [1,5-.alpha.]pyridine (pip) ligands, namely [Ir(ppy)2 (pip)]+, have been synthesized, characterized and their electrochemical, photophysical and electronic properties studied. Seven X-ray structures have been resolved. Excitation of [[Ir(ppy)2 (pip)]+ in acetonitrile solutions at room temperature results in a dual luminescence, strongly quenched by O2. Four complexes show, in absence of O2, a highenergy emission (assigned to a 3MLLCT transition) with two maxima in the blue region of the visible spectra, and a second structured emission (assigned largely to a 3LC .pi.–.pi.* transition). The electrochemical behaviour of all complexes is also reported. (en)
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Title
| - Cationic Heteroleptic Cyclometalated Iridium Complexes with 1-Pyridylimidazo[1,5-alpha]pyridine Ligands: Exploitation of an Efficient Intersystem Crossing
- Cationic Heteroleptic Cyclometalated Iridium Complexes with 1-Pyridylimidazo[1,5-alpha]pyridine Ligands: Exploitation of an Efficient Intersystem Crossing (en)
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skos:prefLabel
| - Cationic Heteroleptic Cyclometalated Iridium Complexes with 1-Pyridylimidazo[1,5-alpha]pyridine Ligands: Exploitation of an Efficient Intersystem Crossing
- Cationic Heteroleptic Cyclometalated Iridium Complexes with 1-Pyridylimidazo[1,5-alpha]pyridine Ligands: Exploitation of an Efficient Intersystem Crossing (en)
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skos:notation
| - RIV/61388955:_____/09:00327323!RIV10-MSM-61388955
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(LC510), P(OC 140), Z(AV0Z40400503)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/09:00327323
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - density functional calculation; fluorescence; intersystem crossing; iridium; phosphorescence (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Chemistry - A European Journal
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Fiedler, Jan
- Salassa, L.
- Gobetto, R.
- Nervi, C.
- Volpi, G.
- Garino, C.
- Hardcastle, K.
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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