About: An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands     Goto   Sponge   NotDistinct   Permalink

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Description
  • The paramagnetic compound [Ru(NO)(Q)(terpy)](PF6)2 (Q = 4,6-Di-tert.-butyl-N-phenyl-o-iminobenzoquinone) was prepared via the intermediates [RuCl(Q)(terpy)](ClO4) and [Ru(NO2)(Q)(terpy)](ClO4). The more stable positional isomer with NO trans to the O donor atom of Q was isolated and characterized. In conjunction with the X-ray crystal structure, IR and EPR studies suggest [RuII(NO+)(Q-)(terpy)]2+ as the most valid oxidation state formulation. DFT calculations confirm oxidation state assignment.
  • The paramagnetic compound [Ru(NO)(Q)(terpy)](PF6)2 (Q = 4,6-Di-tert.-butyl-N-phenyl-o-iminobenzoquinone) was prepared via the intermediates [RuCl(Q)(terpy)](ClO4) and [Ru(NO2)(Q)(terpy)](ClO4). The more stable positional isomer with NO trans to the O donor atom of Q was isolated and characterized. In conjunction with the X-ray crystal structure, IR and EPR studies suggest [RuII(NO+)(Q-)(terpy)]2+ as the most valid oxidation state formulation. DFT calculations confirm oxidation state assignment. (en)
Title
  • An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands
  • An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands (en)
skos:prefLabel
  • An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands
  • An Odd-Electron Complex [Ru-k(NOm)(Q(n))(terpy)](2+) with Two Prototypical Non-Innocent Ligands (en)
skos:notation
  • RIV/61388955:_____/09:00327321!RIV10-MSM-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(KAN100400702), P(OC 139), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 23
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 302761
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/09:00327321
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • nitrosyl complexes; non-innocent ligands; quinones; radical ligands; ruthenium (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [9D2EDBB1CDAF]
http://linked.open...i/riv/nazevZdroje
  • Angewandte Chemie. International Edition in English
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 48
http://linked.open...iv/tvurceVysledku
  • Fiedler, Jan
  • Kaim, W.
  • Lahiri, G. K.
  • Sarkar, B.
  • Záliš, Stanislav
  • Strobel, S.
  • Das, A. K.
  • Duboc, C.
http://linked.open...ain/vavai/riv/wos
  • 000266527800036
http://linked.open...n/vavai/riv/zamer
issn
  • 1433-7851
number of pages
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