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| rdf:type
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| Description
| - The reactions of trans-[MoO(ONOMe)Cl-2] 1 (ONOMe = methylamino-N,N-bis(2-methylene-4,6-dimethylphenolate) dianion) and trans-[MoO(ONOtBu)Cl-2] 2 (ONOtBu = methylamino-N, N-bis(2-methylene-4-methyl-6-tert-butylphenolate) dianion) with PhNCO afforded new imido molybdenum complexes trans-[Mo(NPh)(ONOMe) Cl-2] 3 and trans-[Mo(NPh)(ONOtBu)Cl-2] 4, respectively. As analogous oxotungsten starting materials did not show similar reactivity, corresponding imido tungsten complexes were prepared by the reaction between [W(NPh)Cl-4] with aminobis(phenol)s. These reactions yielded cis- and trans-isomers of dichloro complexes [W(NPh)(ONOMe)Cl-2] 5 and [W(NPh)(ONOtBu)Cl-2] 6, respectively. The molecular structures of 4, cis-6 and trans-6 were verified by X-ray crystallography. Organosubstituted imido tungsten(VI) complex cis-[W(NPh)(ONOtBu)Me-2] 7 was prepared by the transmetallation reaction of 6 (either cis or trans isomer) with methyl magnesium iodide.
- The reactions of trans-[MoO(ONOMe)Cl-2] 1 (ONOMe = methylamino-N,N-bis(2-methylene-4,6-dimethylphenolate) dianion) and trans-[MoO(ONOtBu)Cl-2] 2 (ONOtBu = methylamino-N, N-bis(2-methylene-4-methyl-6-tert-butylphenolate) dianion) with PhNCO afforded new imido molybdenum complexes trans-[Mo(NPh)(ONOMe) Cl-2] 3 and trans-[Mo(NPh)(ONOtBu)Cl-2] 4, respectively. As analogous oxotungsten starting materials did not show similar reactivity, corresponding imido tungsten complexes were prepared by the reaction between [W(NPh)Cl-4] with aminobis(phenol)s. These reactions yielded cis- and trans-isomers of dichloro complexes [W(NPh)(ONOMe)Cl-2] 5 and [W(NPh)(ONOtBu)Cl-2] 6, respectively. The molecular structures of 4, cis-6 and trans-6 were verified by X-ray crystallography. Organosubstituted imido tungsten(VI) complex cis-[W(NPh)(ONOtBu)Me-2] 7 was prepared by the transmetallation reaction of 6 (either cis or trans isomer) with methyl magnesium iodide. (en)
- Reakce trans-[MoO(ONOMe)Cl2] - 1 (ONOMe = methylamino-N,N-bis(2-methylene- 4,6-dimethylfenolat) dianion) a trans-[MoO(ONOtBu)Cl2] - 2 (ONOtBu = methylamino- N,N-bis(2-methylene-4-methyl-6-tert-butylfenolat) dianion) s PhNCO poskytují nové imido komplexy molybdenu trans-[Mo(NPh)(ONOMe)Cl2] - 3 a trans-[Mo(NPh)(ONOtBu)Cl2] - 4. Protože oxo skupina v analogických wolframových komplexech nevykazuje podobnou reaktivitu, wolframové imido komplexy byly připraveny reakcí [W(NPh)Cl4] s aminobisfenoly. Tato reakce poskytuje cis- a trans-isomery příslušných dichloro komplexů [W(NPh)(ONOMe)Cl2] - 5 a [W(NPh)(ONOtBu)Cl2]- 6. Molekulová struktura produktů 4, cis-6 a trans-6 byla potvrzena rentgenovými spektry. Methylovaný derivát imido komplexu wolframu(VI) cis-[W(NPh)(ONOtBu)Me2] - 7 byl připraven z 6 (buď cis nebo trans isomeru) transmetalační reakcí s methylmagnesiumjodidem. (cs)
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| Title
| - Aminobis(phenolate)s of imidomolybdenum(VI) and -tungsten(VI)
- Aminobisfenoláty imidomolybdenu(VI) a imidowolframu(VI) (cs)
- Aminobis(phenolate)s of imidomolybdenum(VI) and -tungsten(VI) (en)
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| skos:prefLabel
| - Aminobis(phenolate)s of imidomolybdenum(VI) and -tungsten(VI)
- Aminobisfenoláty imidomolybdenu(VI) a imidowolframu(VI) (cs)
- Aminobis(phenolate)s of imidomolybdenum(VI) and -tungsten(VI) (en)
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| skos:notation
| - RIV/61388955:_____/09:00322930!RIV09-AV0-61388955
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - P(KAN400100701), Z(AV0Z40400503)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/09:00322930
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - tungsten; molybdenum; imido ligand; aryloxide ligand (en)
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| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Balcar, Hynek
- Sillanpää, R.
- Lehtonen, A.
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| http://linked.open...ain/vavai/riv/wos
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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