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Description
  • Byla provedena první izotopicky invariantní Dunhamova analýza negativního iontu (hydrogensulfidového aniontu SH-) vedoucí k určení Born-Oppenheimerových breakdown parametrů. Pro tuto analýzu byla využita veškerá dostupná infračervená a submilimetrová experimentální data charakterizující 32SH-, 33SH-, 34SH- a 32SD-. Byly vypočítány konstanty rozšíření potenciálové funkce až do šestého řádu. Současně byly ukázány rozdíly v konstrukci potenciálové funkce založené na Morseho potenciálu a konstrukci využívající rozšíření silových konstant. (cs)
  • The first isotopically invariant Dunham analysis of a negative ion (the hydrogen sulfide anion SH-) that uses all available infrared and sub-millimeter wave experimental data on (SH-)-S-32, (SH-)-S-33, (SH-)-S-34, and (SD-)-S-32, yields accurate information on Born-Oppenheimer breakdown parameters. The potential constants of expansion of the potential function up to the sixth order were calculated. Differences between the construction of the potential function based on the Morse potential and that on the base of the power series expansion are shown.
  • The first isotopically invariant Dunham analysis of a negative ion (the hydrogen sulfide anion SH-) that uses all available infrared and sub-millimeter wave experimental data on (SH-)-S-32, (SH-)-S-33, (SH-)-S-34, and (SD-)-S-32, yields accurate information on Born-Oppenheimer breakdown parameters. The potential constants of expansion of the potential function up to the sixth order were calculated. Differences between the construction of the potential function based on the Morse potential and that on the base of the power series expansion are shown. (en)
Title
  • First determination of isotopically invariant parameters of the negative ion-Hydrogen sulfide anion (SH-)
  • První stanovení izotopicky invariantních parametrů negativního iontu - hydrogensulfidový aniont (SH-) (cs)
  • First determination of isotopically invariant parameters of the negative ion-Hydrogen sulfide anion (SH-) (en)
skos:prefLabel
  • First determination of isotopically invariant parameters of the negative ion-Hydrogen sulfide anion (SH-)
  • První stanovení izotopicky invariantních parametrů negativního iontu - hydrogensulfidový aniont (SH-) (cs)
  • First determination of isotopically invariant parameters of the negative ion-Hydrogen sulfide anion (SH-) (en)
skos:notation
  • RIV/61388955:_____/08:00314677!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/06/0216), P(LC06071), P(OC 111), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 368091
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/08:00314677
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • infrared laser spectroscopy; molecular ions; Dunham coeffcients (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [6BACF76E4293]
http://linked.open...i/riv/nazevZdroje
  • Journal of Molecular Spectroscopy
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 249
http://linked.open...iv/tvurceVysledku
  • Kubát, Pavel
  • Střižík, M.
  • Zelinger, Zdeněk
  • Perrin, A.
http://linked.open...ain/vavai/riv/wos
  • 000256463600007
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-2852
number of pages
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