About: Detailed study of fine and hyperfine structures in rotational spectra of the free fluoroformyloxyl radical FCO2 center dot

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About: Detailed study of fine and hyperfine structures in rotational spectra of the free fluoroformyloxyl radical FCO2 center dot Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Více jak 160 nových hyperjemných komponent rotačních přechodů volného fluoroformyloxylového radikálu FCO2. bylo změřeno pražským vysoce rozlišeným spektrometrem v milimetrové oblasti. Frekvence těchto přechodů společně s dostupnými měřenými daty byly analyzovány a byly určeny přesné hodnoty magnetických hyperjemných a jemných parametrů. (cs) More than 160 new hyperfine components of rotational transitions of the free fluoroformyloxyl radical FCO2 center dot have been measured using the Prague millimeter wave high resolution spectrometer. The frequencies of these transitions together with the previously measured data were analyzed in detail and precise values of magnetic hyperfine and fine parameters were obtained. These new parameters significantly improve the values of previously determined hyperfine parameters which were rather unreliable. The new fine and hyperfine parameters obtained in this study are compatible with those of the simultaneously electron paramagnetic resonance study. Besides that, significantly improved ground state rotational and centrifugal distortion constants of the fluoroformyloxyl radical were derived. (C) 2008 American Institute of Physics. More than 160 new hyperfine components of rotational transitions of the free fluoroformyloxyl radical FCO2 center dot have been measured using the Prague millimeter wave high resolution spectrometer. The frequencies of these transitions together with the previously measured data were analyzed in detail and precise values of magnetic hyperfine and fine parameters were obtained. These new parameters significantly improve the values of previously determined hyperfine parameters which were rather unreliable. The new fine and hyperfine parameters obtained in this study are compatible with those of the simultaneously electron paramagnetic resonance study. Besides that, significantly improved ground state rotational and centrifugal distortion constants of the fluoroformyloxyl radical were derived. (C) 2008 American Institute of Physics. (en)
Title	Detailed study of fine and hyperfine structures in rotational spectra of the free fluoroformyloxyl radical FCO2 center dot Detailed study of fine and hyperfine structures in rotational spectra of the free fluoroformyloxyl radical FCO2 center dot (en) Detailní studie jemných a hyperjemných struktur rotačního spektra volného fluoroformyloxylového radikálu FCO2 (cs)
skos:prefLabel	Detailed study of fine and hyperfine structures in rotational spectra of the free fluoroformyloxyl radical FCO2 center dot Detailed study of fine and hyperfine structures in rotational spectra of the free fluoroformyloxyl radical FCO2 center dot (en) Detailní studie jemných a hyperjemných struktur rotačního spektra volného fluoroformyloxylového radikálu FCO2 (cs)
skos:notation	RIV/61388955:_____/08:00314669!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(1ET400400410), P(IAA400400504), P(LC06071), P(OC 110), P(OC 111), Z(AV0Z40400503), Z(MSM6046137307)
http://linked.open...iv/cisloPeriodika	22
http://linked.open...vai/riv/dodaniDat	2009
http://linked.open...aciTvurceVysledku	Šimečková, Marie Urban, Štěpán Zelinger, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	362772
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/08:00314669
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	self-reaction; kinetics; FCO2 (en)
http://linked.open.../riv/klicoveSlovo	kinetics FCO2 self-reaction
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[6707496A9A3A]
http://linked.open...i/riv/nazevZdroje	Journal of Chemical Physics
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	9 (xsd:int)
http://linked.open...vavai/riv/projekt	From a computer controlled spectroscopis experiment to an international database for remote detection of molecules http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20111 Quasioptical Systems and Terahertz Spectroscopy http://linked.opendata.cz/resource/domain/vavai/projekt/OC%20110 Microwave spectroscopy of nitrogen and halogen atmospheric components with significant hyperfine structure of rotational levels
http://linked.open...UplatneniVysledku	2008
http://linked.open...v/svazekPeriodika	128
http://linked.open...iv/tvurceVysledku	Zelinger, Zdeněk Šimečková, Marie Urban, Štěpán Beckers, H. Willner, H. Kania, P. Varga, J. Kolesníková, L. Nová Stříteská, L.
http://linked.open...ain/vavai/riv/wos	000256706300011
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace Physico-chemical methods of analysis and characterization of chemical systems and biosystems
issn	0021-9606
number of pages	8 (xsd:int)

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