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  • A detailed study is presented on the optical absorption of thin films of single wall carbon nanotubes (SWNT). The procedure for the preparation of free-standing semitransparent films of SWNT is used for the fabrication of a working electrode for transmission optical spectroelectrochemistry. The analysis of the potential dependent spectroscopic response of the SWNT film benefits from the widest possible electrochemical window, in which the charging of SWNT can safely be investigated. This electrochemical window is not limited by parasitic electrochemistry and/or galvanic breakdown reactions occurring at supporting electrode materials such as indium-tin oxide conducting glass or semitransparent Pt film, which were employed in earlier studies. Electrochemical doping of SWNT is observable at the optical absorptions, which are assigned to allowed electronic transitions between van Hove singularities in the density of states of SWNT.
  • A detailed study is presented on the optical absorption of thin films of single wall carbon nanotubes (SWNT). The procedure for the preparation of free-standing semitransparent films of SWNT is used for the fabrication of a working electrode for transmission optical spectroelectrochemistry. The analysis of the potential dependent spectroscopic response of the SWNT film benefits from the widest possible electrochemical window, in which the charging of SWNT can safely be investigated. This electrochemical window is not limited by parasitic electrochemistry and/or galvanic breakdown reactions occurring at supporting electrode materials such as indium-tin oxide conducting glass or semitransparent Pt film, which were employed in earlier studies. Electrochemical doping of SWNT is observable at the optical absorptions, which are assigned to allowed electronic transitions between van Hove singularities in the density of states of SWNT. (en)
  • Byla provedena detailní studie optických absorpčních vlastností tenkých filmů z jednostěnných uhlíkových nanotrubic. Dále byly studovány změny optické absorpce zmíněných filmů v závislosti na vloženém potenciálu. (cs)
Title
  • In situ optical spectroelectrochemistry of single-walled carbon nanotube thin films
  • Optická spektroelektrochemie in situ měřená na tenkém filmu z jednostěnných uhlíkových nanotrubic (cs)
  • In situ optical spectroelectrochemistry of single-walled carbon nanotube thin films (en)
skos:prefLabel
  • In situ optical spectroelectrochemistry of single-walled carbon nanotube thin films
  • Optická spektroelektrochemie in situ měřená na tenkém filmu z jednostěnných uhlíkových nanotrubic (cs)
  • In situ optical spectroelectrochemistry of single-walled carbon nanotube thin films (en)
skos:notation
  • RIV/61388955:_____/08:00310179!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LC510), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 10
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 371763
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/08:00310179
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • uv-vis spectroelectrochemistry; cyclic voltammetry; single-walled carbon nanotubes; thin films; doping (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [5931E27C012D]
http://linked.open...i/riv/nazevZdroje
  • Journal of Solid State Electrochemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 12
http://linked.open...iv/tvurceVysledku
  • Dunsch, L.
  • Kalbáč, Martin
  • Kavan, Ladislav
  • Zukalová, Markéta
  • Tarábek, Ján
http://linked.open...ain/vavai/riv/wos
  • 000257208800009
http://linked.open...n/vavai/riv/zamer
issn
  • 1432-8488
number of pages
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