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Description
  • Článek popisuje roli distribuce náboje v polyatomárních reaktantech při určení jejich efektivního náboje v elektrické dvojvrstvě. Užití cTp grafů vyžaduje znalost efektivních nábojů jak reaktantů tak produktů a experimentálně je lze získat z tzv. apparent cTp grafů. Experimentální výsledky získané v naší laboratoři pro 6 různých jednoduchých reakcí přenosu elektronu převážně iontů přechodových kovů jsou popsány zejména z hlediska kinetických parametrů typu efektivních nábojů na reaktantech a tzv. apparent Tafelových koeficientů. (cs)
  • The role of charge distribution in a polyatomic reactant in determining its effective charge in the double layer is discussed. It is shown that the use of a corrected Tafel plot (cTp) requires knowledge of the effective charge on both the reactant and product of a simple electron transfer process. This leads to the use of so called apparent corrected Tafel plots. Data obtained in this laboratory for six different simple electron transfer reactions involving transition metal ions are reviewed, and discussed in terms of their kinetic parameters, namely, the effective charge on the reactant and the apparent Tafel coefficient.
  • The role of charge distribution in a polyatomic reactant in determining its effective charge in the double layer is discussed. It is shown that the use of a corrected Tafel plot (cTp) requires knowledge of the effective charge on both the reactant and product of a simple electron transfer process. This leads to the use of so called apparent corrected Tafel plots. Data obtained in this laboratory for six different simple electron transfer reactions involving transition metal ions are reviewed, and discussed in terms of their kinetic parameters, namely, the effective charge on the reactant and the apparent Tafel coefficient. (en)
Title
  • Charge distribution effects in polyatomic reactants involved in simple electron transfer reactions
  • Charge distribution effects in polyatomic reactants involved in simple electron transfer reactions (en)
  • Vliv rozložení nábojové hustoty v polyatomárních reaktantech na reakce přenosu náboje (cs)
skos:prefLabel
  • Charge distribution effects in polyatomic reactants involved in simple electron transfer reactions
  • Charge distribution effects in polyatomic reactants involved in simple electron transfer reactions (en)
  • Vliv rozložení nábojové hustoty v polyatomárních reaktantech na reakce přenosu náboje (cs)
skos:notation
  • RIV/61388955:_____/08:00309961!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 23
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 359675
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/08:00309961
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • electron transfer kinetics; charge distribution effects; double-layer effects in electrode kinetics (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [B53C36A8D608]
http://linked.open...i/riv/nazevZdroje
  • Electrochimica acta
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 53
http://linked.open...iv/tvurceVysledku
  • Hromadová, Magdaléna
  • Chavis, G. J.
  • Fawcett, W. R.
http://linked.open...ain/vavai/riv/wos
  • 000258975400015
http://linked.open...n/vavai/riv/zamer
issn
  • 0013-4686
number of pages
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