About: Highly porous TiO2 films from anodically deposited titanate hybrids and their photoelectrochemical and photocatalytic activity     Goto   Sponge   NotDistinct   Permalink

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  • Hybrid films of TiO2 and benzoquinone, its derivative 2-methyl-benzoquinone or the dye 2,9,16,23-tetrasulfophthalocyaninatonickel(II) were prepared by anodic electrodeposition from titanium alkoxide solutions. Calcination of the films at 450 degrees C led to removal of the organics and the formation of crystalline and highly porous TiO2 films as seen in XRD and Kr adsorption measurements, respectively. In dye-sensitized solar cells the films achieved an overall light-to-electricity conversion efficiency of 0.8% despite a low film thickness of 0.55 mu m. In the photocatalytic decomposition of methylene blue the films showed photonic efficiencies of up to 0.09% for film thicknesses around 0.5 mu m, which is much higher than those of comparable TiO2 films prepared by sol-gel method.
  • Hybrid films of TiO2 and benzoquinone, its derivative 2-methyl-benzoquinone or the dye 2,9,16,23-tetrasulfophthalocyaninatonickel(II) were prepared by anodic electrodeposition from titanium alkoxide solutions. Calcination of the films at 450 degrees C led to removal of the organics and the formation of crystalline and highly porous TiO2 films as seen in XRD and Kr adsorption measurements, respectively. In dye-sensitized solar cells the films achieved an overall light-to-electricity conversion efficiency of 0.8% despite a low film thickness of 0.55 mu m. In the photocatalytic decomposition of methylene blue the films showed photonic efficiencies of up to 0.09% for film thicknesses around 0.5 mu m, which is much higher than those of comparable TiO2 films prepared by sol-gel method. (en)
  • Hybridní filmy TiO2 a benzochinonu, jeho derivátu 2-methyl-benzochinonu nebo barviva 2,9,16,23-tetrasulfoftalocyaninato niklu(II) byly připraveny anodickou elektrodepozicí z roztoků alkoxidů titanu. Kalcinace filmů při 450 oC vedla k odstranění organické složky a k tvorbě krystalických a vysoce porézních filmů TiO2, jak bylo zjištěno XRD a adsorpcí kryptonu. V solárních článcích sensitizovaných barvivy filmy dosahují celkové účinnosti konverze světla na elektřinu 0.8% přes malou tloušťku filmů dosahující 0.55 mikrometrů. Ve fotokatalytické dekompozici methylenové modře filmy vykazují fotonickou účinnost až 0.09% pro filmy o tloušťce kolem 0.5 mikrometru, což je mnohem více než pro srovnatelné TiO2 filmy připravené metodou sol-gel. (cs)
Title
  • Highly porous TiO2 films from anodically deposited titanate hybrids and their photoelectrochemical and photocatalytic activity
  • Highly porous TiO2 films from anodically deposited titanate hybrids and their photoelectrochemical and photocatalytic activity (en)
  • Vysoce porézní filmy films z anodicky deponovaných titanátových hybridů a jejich fotoelektrochemická a fotokatalytická aktivita (cs)
skos:prefLabel
  • Highly porous TiO2 films from anodically deposited titanate hybrids and their photoelectrochemical and photocatalytic activity
  • Highly porous TiO2 films from anodically deposited titanate hybrids and their photoelectrochemical and photocatalytic activity (en)
  • Vysoce porézní filmy films z anodicky deponovaných titanátových hybridů a jejich fotoelektrochemická a fotokatalytická aktivita (cs)
skos:notation
  • RIV/61388955:_____/08:00309561!RIV09-AV0-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(1M0577), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 1-3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 370119
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/08:00309561
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • electrodeposition; titanium dioxide; dye-sensitized solar cells; Kr adsorption (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [726BD51076E0]
http://linked.open...i/riv/nazevZdroje
  • Microporous and Mesoporous Materials
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 111
http://linked.open...iv/tvurceVysledku
  • Rathouský, Jiří
  • Wark, M.
  • Maekawa, M.
  • Oerkermann, T.
  • Wessels, K.
  • Yoshida, T.
http://linked.open...ain/vavai/riv/wos
  • 255847100010
http://linked.open...n/vavai/riv/zamer
issn
  • 1387-1811
number of pages
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