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  • The behaviour Of L-alpha-lecithin (DPPC) was studied at the water/1,2-dichloroethane interface within a range of interfacial potential differences below the zero-charge potential difference, using surface tension and voltammetric measurements. The general five-step model, established in Parts I and II of this series, has been confirmed. The surface pressure of DPPC adsorbed at the interface exhibits a maximum in acidic media close to the zero-charge potential difference, E-pzc, of the base electrolytes. It is demonstrated that, in contrast to the potentials higher than E-pzc, where the change in the surface pressure is due to desorption of the protonated form of DPPC, the observed change in the surface pressure at interfacial potential differences below E-pzc can be explained by alterations in the concentrations of the adsorbed zwitter-ionic and protonated forms of DPPC governed by the general acid/base equilibrium.
  • The behaviour Of L-alpha-lecithin (DPPC) was studied at the water/1,2-dichloroethane interface within a range of interfacial potential differences below the zero-charge potential difference, using surface tension and voltammetric measurements. The general five-step model, established in Parts I and II of this series, has been confirmed. The surface pressure of DPPC adsorbed at the interface exhibits a maximum in acidic media close to the zero-charge potential difference, E-pzc, of the base electrolytes. It is demonstrated that, in contrast to the potentials higher than E-pzc, where the change in the surface pressure is due to desorption of the protonated form of DPPC, the observed change in the surface pressure at interfacial potential differences below E-pzc can be explained by alterations in the concentrations of the adsorbed zwitter-ionic and protonated forms of DPPC governed by the general acid/base equilibrium. (en)
Title
  • Adsorption and ion-pairing interactions of phospholipids in the system of two immiscible electrolyte solutions - Part III: The behaviour of a lecithin layer...
  • Adsorption and ion-pairing interactions of phospholipids in the system of two immiscible electrolyte solutions - Part III: The behaviour of a lecithin layer... (en)
skos:prefLabel
  • Adsorption and ion-pairing interactions of phospholipids in the system of two immiscible electrolyte solutions - Part III: The behaviour of a lecithin layer...
  • Adsorption and ion-pairing interactions of phospholipids in the system of two immiscible electrolyte solutions - Part III: The behaviour of a lecithin layer... (en)
skos:notation
  • RIV/61388955:_____/08:00309481!RIV10-MSM-61388955
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(LC06063), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 354961
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/08:00309481
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • liquid/liquid interfaces; surface tension; adsorption of phospholipids (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [486F98B55AD3]
http://linked.open...i/riv/nazevZdroje
  • Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 612
http://linked.open...iv/tvurceVysledku
  • Mareček, Vladimír
  • Štulík, K.
  • Jänchenová, Hana
http://linked.open...ain/vavai/riv/wos
  • 000252600400005
http://linked.open...n/vavai/riv/zamer
issn
  • 1572-6657
number of pages
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