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rdf:type
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Description
| - The behaviour Of L-alpha-lecithin (DPPC) was studied at the water/1,2-dichloroethane interface within a range of interfacial potential differences below the zero-charge potential difference, using surface tension and voltammetric measurements. The general five-step model, established in Parts I and II of this series, has been confirmed. The surface pressure of DPPC adsorbed at the interface exhibits a maximum in acidic media close to the zero-charge potential difference, E-pzc, of the base electrolytes. It is demonstrated that, in contrast to the potentials higher than E-pzc, where the change in the surface pressure is due to desorption of the protonated form of DPPC, the observed change in the surface pressure at interfacial potential differences below E-pzc can be explained by alterations in the concentrations of the adsorbed zwitter-ionic and protonated forms of DPPC governed by the general acid/base equilibrium.
- The behaviour Of L-alpha-lecithin (DPPC) was studied at the water/1,2-dichloroethane interface within a range of interfacial potential differences below the zero-charge potential difference, using surface tension and voltammetric measurements. The general five-step model, established in Parts I and II of this series, has been confirmed. The surface pressure of DPPC adsorbed at the interface exhibits a maximum in acidic media close to the zero-charge potential difference, E-pzc, of the base electrolytes. It is demonstrated that, in contrast to the potentials higher than E-pzc, where the change in the surface pressure is due to desorption of the protonated form of DPPC, the observed change in the surface pressure at interfacial potential differences below E-pzc can be explained by alterations in the concentrations of the adsorbed zwitter-ionic and protonated forms of DPPC governed by the general acid/base equilibrium. (en)
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Title
| - Adsorption and ion-pairing interactions of phospholipids in the system of two immiscible electrolyte solutions - Part III: The behaviour of a lecithin layer...
- Adsorption and ion-pairing interactions of phospholipids in the system of two immiscible electrolyte solutions - Part III: The behaviour of a lecithin layer... (en)
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skos:prefLabel
| - Adsorption and ion-pairing interactions of phospholipids in the system of two immiscible electrolyte solutions - Part III: The behaviour of a lecithin layer...
- Adsorption and ion-pairing interactions of phospholipids in the system of two immiscible electrolyte solutions - Part III: The behaviour of a lecithin layer... (en)
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skos:notation
| - RIV/61388955:_____/08:00309481!RIV10-MSM-61388955
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(LC06063), Z(AV0Z40400503)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/08:00309481
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - liquid/liquid interfaces; surface tension; adsorption of phospholipids (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Electroanalytical Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
| |
http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Mareček, Vladimír
- Štulík, K.
- Jänchenová, Hana
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http://linked.open...ain/vavai/riv/wos
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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