| Attributes | Values |
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| rdf:type
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| Description
| - Ve vodě rozpustné jedno- a dvojjaderné Ir, Rh a Ru komplexy obsahující současně „měkké“ chelátující organické a „tvrdé“ hydrofilní ligandy jsou slibnými hydrogenačními katalyzátory díky své schopnosti pH-selektivně koordinovat vodu. Elektrochemické studium oxidace i redukce serií těchto sloučenin, které obsahují bipyrimidinové ligandy umožnilo charakterizovat jejich redox vlastnosti a intramolekulární elektronické interakce a korelovat je s katalytickou aktivitou. (cs)
- The mononuclear complexes [(eta(5)-C5Me5)IrCl(L-1)] (1), [(eta(5)-C5Me5)RhCl(L-1)] (2), [(eta(6)-p-Pr´C6H4Me)RuCl(L-1)] (3) and [(eta(6)- C6Me6)RuCl(L-1)] (4) have been synthesised from pyrazine-2-carboxylic acid (HL1) and the corresponding complexes [{(eta(5)- C5Me5)IrCl2)(2)], [{(eta(5)-C5Me5)RhCl2)(2)], [{(eta(6)-p-Pr´C6H4Me)RuCl2}(2)], and [{(eta(6)-C6Me6)RuCl2}(2)], respectively. The related dinuclear complexes [{(eta(5)-C5Me5)IrCl)(2)(mu-L-2)] (5), [{(eta(5)-C5Me5)RhCl}(2)(mu-L-2)] (6), [{(n(6)-p-(PrC6H4Me)-C-i)RuCl}(2)(mu-L-2)] (7) and [(eta(6)-C6Me6)R-uCl} (2)(mu-L-2)] (8) have been obtained in a similar manner from pyrazine-2,5-dicarboxylic acid (H2L2). Compounds isomeric to the latter series, [{(eta(5)-C5Me5)IrCl}(2)(mu-L-3)] (9), [{(eta(5)-C5Me5)RhCl}(2)(mu-L-3)] (10), [{(p-Pr´C6H4Me)RuCl}(2)(mu-L-3)] (11) and [{(eta(6)-C6Me6)RuCl}(2)(mu-L-3 )] (12), have been prepared by using pyrazine-2,3-dicarboxylic acid (H2L3) instead of H2L2.
- The mononuclear complexes [(eta(5)-C5Me5)IrCl(L-1)] (1), [(eta(5)-C5Me5)RhCl(L-1)] (2), [(eta(6)-p-Pr´C6H4Me)RuCl(L-1)] (3) and [(eta(6)- C6Me6)RuCl(L-1)] (4) have been synthesised from pyrazine-2-carboxylic acid (HL1) and the corresponding complexes [{(eta(5)- C5Me5)IrCl2)(2)], [{(eta(5)-C5Me5)RhCl2)(2)], [{(eta(6)-p-Pr´C6H4Me)RuCl2}(2)], and [{(eta(6)-C6Me6)RuCl2}(2)], respectively. The related dinuclear complexes [{(eta(5)-C5Me5)IrCl)(2)(mu-L-2)] (5), [{(eta(5)-C5Me5)RhCl}(2)(mu-L-2)] (6), [{(n(6)-p-(PrC6H4Me)-C-i)RuCl}(2)(mu-L-2)] (7) and [(eta(6)-C6Me6)R-uCl} (2)(mu-L-2)] (8) have been obtained in a similar manner from pyrazine-2,5-dicarboxylic acid (H2L2). Compounds isomeric to the latter series, [{(eta(5)-C5Me5)IrCl}(2)(mu-L-3)] (9), [{(eta(5)-C5Me5)RhCl}(2)(mu-L-3)] (10), [{(p-Pr´C6H4Me)RuCl}(2)(mu-L-3)] (11) and [{(eta(6)-C6Me6)RuCl}(2)(mu-L-3 )] (12), have been prepared by using pyrazine-2,3-dicarboxylic acid (H2L3) instead of H2L2. (en)
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| Title
| - Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry
- Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry (en)
- Jedno a dvoujaderné komplexy rhodia, iridia a ruthenia obsahujíci karboxylátové pyrazinové ligandy: Syntéza, molekulová struktura, elektrochemie a katalytické vlastnosti (cs)
|
| skos:prefLabel
| - Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry
- Mono and dinuclear iridium, rhodium and ruthenium complexes containing chelating carboxylato pyrazine ligands: Synthesis, molecular structure and electrochemistry (en)
- Jedno a dvoujaderné komplexy rhodia, iridia a ruthenia obsahujíci karboxylátové pyrazinové ligandy: Syntéza, molekulová struktura, elektrochemie a katalytické vlastnosti (cs)
|
| skos:notation
| - RIV/61388955:_____/07:00085408!RIV08-MSM-61388955
|
| http://linked.open.../vavai/riv/strany
| |
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(LC06070), P(LC510), Z(AV0Z40400503), Z(MSM0021620857)
|
| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
| |
| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/07:00085408
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - dinuclear complexes; iridium; rhodium; ruthenium; electrochemistry (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
|
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
|
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Štěpnička, P.
- Ludvík, Jiří
- Süss-Fink, G.
- Therrien, B.
- Govindaswamy, P.
|
| http://linked.open...n/vavai/riv/zamer
| |
| issn
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| number of pages
| |
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