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| Description
| - The effect of lithium ion on the ordering of water in water-saturated nitrobenzene has been probed by H-2 NMR, diffusion ordered spectroscopy and neutron scattering. It was shown that increased water concentration in LiClO4/wet nitrobenzene results in the formation of a metastable solvatomer with mixed water and nitrobenzene character, Li-(W/NB)(+). This species is shown to decay over hours to two solvatomers, one dominated by nitrobenzene Li-(NB)(+) and the other dominated by water Li-(W)(+). To confirm the assignment of these solvation states, diffusion ordered deuterium NMR spectroscopy has been used to elucidate the hydrodynamic radii of these solvatomers. Neutron scattering yields vibrational spectroscopy information that shows how addition of lithium to the nitrobenzene/water system results in relatively slow self-organization of the water environment (hours).
- The effect of lithium ion on the ordering of water in water-saturated nitrobenzene has been probed by H-2 NMR, diffusion ordered spectroscopy and neutron scattering. It was shown that increased water concentration in LiClO4/wet nitrobenzene results in the formation of a metastable solvatomer with mixed water and nitrobenzene character, Li-(W/NB)(+). This species is shown to decay over hours to two solvatomers, one dominated by nitrobenzene Li-(NB)(+) and the other dominated by water Li-(W)(+). To confirm the assignment of these solvation states, diffusion ordered deuterium NMR spectroscopy has been used to elucidate the hydrodynamic radii of these solvatomers. Neutron scattering yields vibrational spectroscopy information that shows how addition of lithium to the nitrobenzene/water system results in relatively slow self-organization of the water environment (hours). (en)
- Pomocí metod 2H NMR, %22diffusion ordered spectroscopy%22 a difrakce neutronů byl sledován vliv litných iontů na organizaci molekul vody v nitrobenzenu nasyceném vodou. Bylo ukázáno, že se zvyšující se koncentrací vody v nitrobenzenovém roztoku LiClO4 vzniká matastabliní solvatomer se solvatačním obalem tvořeným molekulami vody a nitrobenzenu , Li(W/NB). Tyto částice se pomalu rozkládají (řadu hodin) na dva solavatomery se solvatačním obale tvořeným převážně molekulami vody Li(W) a nitrobenzenu Li(NB). Hydrodynamické poloměry solvatomerů byly stanoveny metodou DOSY (diffusion ordered spectroscopy). Difrakce neutronů (vibrační spektrosopie) poskytla informace ukazující na pomalou (řádově hodiny) reorganizaci molekul vody po přidání litných iontů k systému voda/nitrobenzen. (cs)
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| Title
| - Self-organization of water in lithium/nitrobenzene system
- Self-organization of water in lithium/nitrobenzene system (en)
- Organizace molekul vody v systému litná sůl/nitrobenzen (cs)
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| skos:prefLabel
| - Self-organization of water in lithium/nitrobenzene system
- Self-organization of water in lithium/nitrobenzene system (en)
- Organizace molekul vody v systému litná sůl/nitrobenzen (cs)
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| skos:notation
| - RIV/61388955:_____/07:00084924!RIV08-MSM-61388955
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| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - P(LC06063), V, Z(AV0Z40400503)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
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| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/07:00084924
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| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - immiscible electrolyte-solutions; ion-transfer; selective hydration (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Journal of Physical Chemistry B
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| http://linked.open...in/vavai/riv/obor
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| http://linked.open...ichTvurcuVysledku
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| http://linked.open...cetTvurcuVysledku
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| http://linked.open...vavai/riv/projekt
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| http://linked.open...UplatneniVysledku
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| http://linked.open...v/svazekPeriodika
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| http://linked.open...iv/tvurceVysledku
| - Mareček, Vladimír
- Janata, J.
- Gelbaum, L. T.
- Leisen, J.
- Moakes, G.
- Daemen, L. L.
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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