| Attributes | Values |
|---|
| rdf:type
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| Description
| - Komplexy cis-MCl2(big), big = bis(1-methylimidazol-2-yl)glyoxal, M = Pt, Pd, byly připraveny a charakterizovány elektrochemií, spektroskopií, a pro M = Pt rentgenovou strukturní analýzou. Sedmičlenný chelátový kruh vytvořený prostřednictvím N,N´ koordinace big ligandu ukazuje vaničkovou konformaci ve shodě s výsledky DFT výpočtů. Žádná významná intermolekulární interakce nebyla pozorována u sloučeniny platiny. Oba PdII a PtII komplexy podléhají reversibilní jednoelektronové redukci v dichlormethanu; redukovaná sloučenina palladia se rozpadá při teplotách nad -30oC. Elektronová paramagnetická resonance (EPR), UV-VIS- a IR spektroelektrochemie byly použity k studiu monoaniontů. (cs)
- Complexes cis-MCl2(big), big = bis(1-methylimidazol-2-yl)glyoxal, M = Pt, Pd, were prepared and characterized through electrochemistry, spectroscopy, and for M = Pt, by X-ray structure analysis. The seven-membered chelate ring formed through N,N´ coordination of the ligand big shows a boat conformation in agreement with density functional theory (DFT) calculation results. No significant intermolecular interactions were observed for the platinum compound. Both the PdII and PtII complexes undergo reversible one-electron reduction in dichloromethane; the reduced palladium compound disintegrates above -30oC. Electron paramagnetic resonance (EPR), UV-Vis-, and IR spectroelectrochemistry studies were employed to study the monoanions.
- Complexes cis-MCl2(big), big = bis(1-methylimidazol-2-yl)glyoxal, M = Pt, Pd, were prepared and characterized through electrochemistry, spectroscopy, and for M = Pt, by X-ray structure analysis. The seven-membered chelate ring formed through N,N´ coordination of the ligand big shows a boat conformation in agreement with density functional theory (DFT) calculation results. No significant intermolecular interactions were observed for the platinum compound. Both the PdII and PtII complexes undergo reversible one-electron reduction in dichloromethane; the reduced palladium compound disintegrates above -30oC. Electron paramagnetic resonance (EPR), UV-Vis-, and IR spectroelectrochemistry studies were employed to study the monoanions. (en)
|
| Title
| - Reversibly Reducible cis-Dichloroplatinum(II) and cis-Dichloropalladium(II) Complexes of Bis(1-methylimidazol-2-yl)glyoxal
- Reversibilně redukovatelné komplexy cis-dichloroplatiny(II) a cis-dichloropalladia(II) s bis(1-methylimidazol-2-yl)glyoxalem (cs)
- Reversibly Reducible cis-Dichloroplatinum(II) and cis-Dichloropalladium(II) Complexes of Bis(1-methylimidazol-2-yl)glyoxal (en)
|
| skos:prefLabel
| - Reversibly Reducible cis-Dichloroplatinum(II) and cis-Dichloropalladium(II) Complexes of Bis(1-methylimidazol-2-yl)glyoxal
- Reversibilně redukovatelné komplexy cis-dichloroplatiny(II) a cis-dichloropalladia(II) s bis(1-methylimidazol-2-yl)glyoxalem (cs)
- Reversibly Reducible cis-Dichloroplatinum(II) and cis-Dichloropalladium(II) Complexes of Bis(1-methylimidazol-2-yl)glyoxal (en)
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| skos:notation
| - RIV/61388955:_____/07:00084288!RIV08-MSM-61388955
|
| http://linked.open.../vavai/riv/strany
| |
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(IAA400400505), P(OC 140), Z(AV0Z40400503)
|
| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/07:00084288
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - cis-dichloroplatinum complexes; electrochemistry; spectroscopy (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
|
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| |
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Fiedler, Jan
- Kaim, W.
- Bulak, E.
- Schwederski, B.
- Varnali, T.
- Lissner, F.
- Sarper, O.
- Leboschka, M.
- Schleid, T.
|
| http://linked.open...n/vavai/riv/zamer
| |
| issn
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| number of pages
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