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  • Large-scale plasma was created in molecular gases (CO, CO2, N2, H2O) and their mixtures by high-power laser-induced dielectric breakdown (LIDB). Compositions of the mixtures used are those suggested for the early earth´s atmosphere of neutral and/or mildly reducing character. Time-integrated optical spectra emitted from the laser spark have been measured and analyzed. The spectra of the plasma generated in the CO-containing mixtures are dominated by emission of both C2 and CN radicals. A vibrational temperature of cca 104 K was determined according to an intensity distribution in a vibronic structure of the CN (B2.SIGMA.+.sub/sub.-.SIGMA.+g) violet band. For comparison, the NH3-CH4-H2-H2O mixture has been irradiated as a model of the strongly reducing version of the early earth´s atmosphere. In this mixture, excited CN seems to be significantly less abundant than C2.
  • Large-scale plasma was created in molecular gases (CO, CO2, N2, H2O) and their mixtures by high-power laser-induced dielectric breakdown (LIDB). Compositions of the mixtures used are those suggested for the early earth´s atmosphere of neutral and/or mildly reducing character. Time-integrated optical spectra emitted from the laser spark have been measured and analyzed. The spectra of the plasma generated in the CO-containing mixtures are dominated by emission of both C2 and CN radicals. A vibrational temperature of cca 104 K was determined according to an intensity distribution in a vibronic structure of the CN (B2.SIGMA.+.sub/sub.-.SIGMA.+g) violet band. For comparison, the NH3-CH4-H2-H2O mixture has been irradiated as a model of the strongly reducing version of the early earth´s atmosphere. In this mixture, excited CN seems to be significantly less abundant than C2. (en)
  • Byla vytvořena plazma v molekulárních plynech (CO, CO2, N2, H2O) a jejich směsích metodou vysoce energetické laserové jiskry. Složení použitých směsí odpovídalo rané atmosféře Země neutrálního a/nebo lehce redukčního charakteru. Byla změřena a analyzována časově nerozlišená spektra záření laserové jiskry. Ve spektrech plasmy, vzniklé ve směsích obsahujících CO, byla dominantní emise C2 a CN radikálů. Vibrační teplota kolem 104 K byla určena z analýzy distribuce intenzit vibronické struktury CN (B2.SIGMA.+.sub/sub.-.SIGMA.+g) pásu v UV oblasti. Pro srovnání byla ozářena směs CH4 - NH3 - N2 - H2O jako příklad silně redukčního typu rané zemské atmosféry. V této směsi byl mnohem menší výskyt excitovaných CN částic než C2. Experimenty s laserovou jiskrou v molekulárních plynech nebyly prováděny pouze ve statickém uspořádání, ale také v plynné trysce (gas-puff target) umístěné ve vakuové interakční komoře. (cs)
Title
  • Optical and X-ray emission spectroscopy of high-power laser-induced dielectric breakdown in molecular gases and their mixtures
  • Optická a rentgenová emisní spektroskopie vysoce energetické laserové jiskry v molekulárních plynech a jejich směsích (cs)
  • Optical and X-ray emission spectroscopy of high-power laser-induced dielectric breakdown in molecular gases and their mixtures (en)
skos:prefLabel
  • Optical and X-ray emission spectroscopy of high-power laser-induced dielectric breakdown in molecular gases and their mixtures
  • Optická a rentgenová emisní spektroskopie vysoce energetické laserové jiskry v molekulárních plynech a jejich směsích (cs)
  • Optical and X-ray emission spectroscopy of high-power laser-induced dielectric breakdown in molecular gases and their mixtures (en)
skos:notation
  • RIV/61388955:_____/06:00044414!RIV07-AV0-61388955
http://linked.open.../vavai/riv/strany
  • 12113;12120
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/06/1278), P(LC528), Z(AV0Z10100521), Z(AV0Z40400503), Z(AV0Z40550506)
http://linked.open...iv/cisloPeriodika
  • 44
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 490699
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/06:00044414
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • X-ray spectroscopy; LIDB; optical emission spectra (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [D9B5DD085FCE]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry. A
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 110
http://linked.open...iv/tvurceVysledku
  • Civiš, Svatopluk
  • Juha, Libor
  • Cihelka, Jaroslav
  • Skála, Jiří
  • Bittner, Michal
  • Pfeifer, Miroslav
  • Ryc, L.
  • Bartnik, A.
  • Fiedorowicz, H.
  • Babánková, Dagmar
  • Šedivcová, Tereza
  • Mikolajczyk, J.
http://linked.open...n/vavai/riv/zamer
issn
  • 1089-5639
number of pages
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