| Attributes | Values |
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| rdf:type
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| Description
| - Constant Current Chronopotentiometric Stripping Analysis using adsorptive accumulation and negative current (AdSCP) was applied as an alternative for the study of metal complexation of glutathione (GSH) or .gamma.-Glu-Cys)2-Gly (PC2) with zinc ions on hanging mercury drop electrode. The behavior of the formed Zn-complexes was studied using voltammetric and chronopotentiometric methods. A multivariate curve resolution method by alternating least-squares (MCR-ALS) applied to DP voltammetric and chronopotentiometric measurements of Zn-PC2 system made possible the formulation of a complexation model. Moreover, the use of small currents in AdSCP allows one to obtain acceptable sensitivities and signal separation at very low concentrations, which is important in peptide studies under conditions similar to these of natural media.
- Constant Current Chronopotentiometric Stripping Analysis using adsorptive accumulation and negative current (AdSCP) was applied as an alternative for the study of metal complexation of glutathione (GSH) or .gamma.-Glu-Cys)2-Gly (PC2) with zinc ions on hanging mercury drop electrode. The behavior of the formed Zn-complexes was studied using voltammetric and chronopotentiometric methods. A multivariate curve resolution method by alternating least-squares (MCR-ALS) applied to DP voltammetric and chronopotentiometric measurements of Zn-PC2 system made possible the formulation of a complexation model. Moreover, the use of small currents in AdSCP allows one to obtain acceptable sensitivities and signal separation at very low concentrations, which is important in peptide studies under conditions similar to these of natural media. (en)
- Chronopotenciometrická rozpouštěcí analýza na visící rtuťové kapkové elektrodě, s aplikací adsorptivní akumulace a záporného rozpouštěcího proudu (AdSCP), byla použita pro studium komplexace glutathionu (GSH) a .gamma.-Glu-Cys)2-Gly (PC2) s ionty zinku. Chování vzniklých Zn-komplexů bylo studováno pomocí voltametrických a chronopotenciometrických metod. Metoda multivariačního rozlišení křivek a alternujících nejmenších čtverců (MCR-ALS) byla aplikována na měření DP voltametrie a chronopotenciometrie, což umožnilo navržení komplexačního modelu pro Zn- PC2 systém. Kromě toho, použití malých proudů v AdSCP znamená dosažení přijatelné citlivosti a rozlišení signálů při velmi malých koncentracích, což je významné pro studium peptidů za podmínek obdobných přírodnímu prostředí. (cs)
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| Title
| - Adsorptive accumulation in constant current stripping chronopotentiometry as an alternative for the electrochemical study of metal complexation by thiol–containing peptides
- Adsorptive accumulation in constant current stripping chronopotentiometry as an alternative for the electrochemical study of metal complexation by thiol–containing peptides (en)
- Adsorptivní akumulace v rozpouštěcí chronopotenciometrii s konstantním proudem jako alternativa pro elektrochemické studium komplexace kovů peptidy s thiolovou skupinou (cs)
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| skos:prefLabel
| - Adsorptive accumulation in constant current stripping chronopotentiometry as an alternative for the electrochemical study of metal complexation by thiol–containing peptides
- Adsorptive accumulation in constant current stripping chronopotentiometry as an alternative for the electrochemical study of metal complexation by thiol–containing peptides (en)
- Adsorptivní akumulace v rozpouštěcí chronopotenciometrii s konstantním proudem jako alternativa pro elektrochemické studium komplexace kovů peptidy s thiolovou skupinou (cs)
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| skos:notation
| - RIV/61388955:_____/06:00039315!RIV07-AV0-61388955
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| http://linked.open.../vavai/riv/strany
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| http://linked.open...avai/riv/aktivita
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| http://linked.open...avai/riv/aktivity
| - P(OC D21.002), Z(AV0Z40400503)
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| http://linked.open...iv/cisloPeriodika
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| http://linked.open...vai/riv/dodaniDat
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| http://linked.open...aciTvurceVysledku
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| http://linked.open.../riv/druhVysledku
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| http://linked.open...iv/duvernostUdaju
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| http://linked.open...titaPredkladatele
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| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/06:00039315
|
| http://linked.open...riv/jazykVysledku
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| http://linked.open.../riv/klicovaSlova
| - stripping chronopotentiometry; adsorptive accumulation; phytochelatins; glutathione (en)
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| http://linked.open.../riv/klicoveSlovo
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| http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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| http://linked.open...ontrolniKodProRIV
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| http://linked.open...i/riv/nazevZdroje
| - Journal of the Electroanalytical Chemistry and Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
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| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Šestáková, Ivana
- Diaz-Cruz, J. M.
- Arino, C.
- Serrano, N.
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| http://linked.open...n/vavai/riv/zamer
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| issn
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| number of pages
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