About: One-electron reduction of an %22extended viologen%22 p-phenyle-bis-4,4´-(aryl-2,6-diphenylpyridinium) dication

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About: One-electron reduction of an %22extended viologen%22 p-phenyle-bis-4,4´-(aryl-2,6-diphenylpyridinium) dication Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Jednoelektronová redukce „viologenového řetězce“ dikationtu 1 poskytuje červený kationradikál 2, pro který je charakteristická silná absorbce v oblasti blízkého infračerveného záření. Kationradikál byl generován a prostudován užitím pulsní rádiolýzy, elektrochemických metod, redox titrací, UV-Vis a EPR metod. Všechny výsledky jsou kompatibilní s úplně delokalizovanou elektronickou strukturou 2. (cs) One-electron reduction of the %22extended viologen%22 dication 1 yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2. One-electron reduction of the %22extended viologen%22 dication 1 yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2. (en)
Title	One-electron reduction of an %22extended viologen%22 p-phenyle-bis-4,4´-(aryl-2,6-diphenylpyridinium) dication One-electron reduction of an %22extended viologen%22 p-phenyle-bis-4,4´-(aryl-2,6-diphenylpyridinium) dication (en) Jednoelektronová redukce „viologenového řetězce“ p-fenylen-bis-4,4´-(1-aryl-2,6-difenylpyridinium) dokationtu (cs)
skos:prefLabel	One-electron reduction of an %22extended viologen%22 p-phenyle-bis-4,4´-(aryl-2,6-diphenylpyridinium) dication One-electron reduction of an %22extended viologen%22 p-phenyle-bis-4,4´-(aryl-2,6-diphenylpyridinium) dication (en) Jednoelektronová redukce „viologenového řetězce“ p-fenylen-bis-4,4´-(1-aryl-2,6-difenylpyridinium) dokationtu (cs)
skos:notation	RIV/61388955:_____/05:00024444!RIV06-AV0-61388955
http://linked.open.../vavai/riv/strany	10862;10869
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/03/0821), P(GA203/04/0921), P(IAA400400505), P(LC510), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika	48
http://linked.open...vai/riv/dodaniDat	2006
http://linked.open...aciTvurceVysledku	Fiedler, Jan Pospíšil, Lubomír Hromadová, Magdaléna Gál, Miroslav
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	534565
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/05:00024444
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	molecular electronics; electrochemistry; redox titration; UV-visible (en)
http://linked.open.../riv/klicoveSlovo	molecular electronics electrochemistry UV-visible redox titration
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[E8FC87A408F3]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry. A
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	12 (xsd:int)
http://linked.open...vavai/riv/projekt	Center of nanotechnology and materials for nanoelectronics Electron transfer to new supramolecular complexes, large molecules with multiple active centers and ordered structures Synthesis of linear pyridinium-phenylene oligomers for use in molecular electronic Redox reactions of free radicals, reactivity in presence of host molecules
http://linked.open...UplatneniVysledku	2005
http://linked.open...v/svazekPeriodika	109
http://linked.open...iv/tvurceVysledku	Fiedler, Jan Gál, Miroslav Hromadová, Magdaléna Pospíšil, Lubomír Valášek, M. Miller, J. R. Kirby, J. P. Michl, J. Pecka, J. Funston, A. Rempala, P. Zawada, Z.
http://linked.open...n/vavai/riv/zamer	Struktura, reaktivita a dynamika molekulárních a biomolekulárních systémů: teorie, experiment, aplikace
issn	1089-5639
number of pages	8 (xsd:int)

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