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Description
  • Polymerací povrchově aktivních derivátů pyrrolu na rozhraní voda|1,2-dichloretan vzniká kompaktní film. Byly syntetizovány nové monomery se dvěma pyrrolovými skupinami v molekule. Polymerace těchto monomerů probíhá snadněji a hustota polymerní vrstvy je vyšší než u monomerů s jednou pyrrolovou skupinou v molekule. Tvorba polymerní vrstvy byla sledována cyklickou voltametrií za přítomnosti iontů různých velikostí a nábojů, přenášených přes rozhraní. Bylo ukázáno, že permeabilitu polymerní vrstvy lze ovlivnit přítomností povrchově aktivních derivátů cyklodextrinu během polymerace. (cs)
  • Polymerization of surface active derivatives of pyrrole at the water[1,2-dichloroethane interface leads to the formation of a compact layer. New monomers have been synthesized with two pyrrole units in the molecule. Polymerization of these monomers proceeds at a lower potential and the density of the polymer layer is higher compared with monomers with one pyrrole unit in the molecule. Formation of the polymer layer has been monitored by cyclic voltammetry in the presence of transferable ions of different size and charge. Permeability of the polymer layer can be affected by the presence of a surface active derivative of cyclodextrin in the polymerization process.
  • Polymerization of surface active derivatives of pyrrole at the water[1,2-dichloroethane interface leads to the formation of a compact layer. New monomers have been synthesized with two pyrrole units in the molecule. Polymerization of these monomers proceeds at a lower potential and the density of the polymer layer is higher compared with monomers with one pyrrole unit in the molecule. Formation of the polymer layer has been monitored by cyclic voltammetry in the presence of transferable ions of different size and charge. Permeability of the polymer layer can be affected by the presence of a surface active derivative of cyclodextrin in the polymerization process. (en)
Title
  • Compact poly-pyrrole layers formed at a liquid vertical bar liquid interface
  • Compact poly-pyrrole layers formed at a liquid vertical bar liquid interface (en)
  • Syntéza kompaktních poly-pyrrolových filmů na rozhraní kapalina|kapalina (cs)
skos:prefLabel
  • Compact poly-pyrrole layers formed at a liquid vertical bar liquid interface
  • Compact poly-pyrrole layers formed at a liquid vertical bar liquid interface (en)
  • Syntéza kompaktních poly-pyrrolových filmů na rozhraní kapalina|kapalina (cs)
skos:notation
  • RIV/61388955:_____/05:00000586!RIV06-AV0-61388955
http://linked.open.../vavai/riv/strany
  • 293;299
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/03/0822), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 515774
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/05:00000586
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • liquid/liquid interfaces; polymer layer; adsorption; polymerization (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [90479B070A6D]
http://linked.open...i/riv/nazevZdroje
  • Journal of the Electroanalytical Chemistry and Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 575
http://linked.open...iv/tvurceVysledku
  • Mareček, Vladimír
  • Budka, J.
  • Jänchenová, Hana
  • Stibor, I.
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-0728
number of pages
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