About: The Submillimeter-wave Spectrum of the Chloromethyl Radical, CH2Cl, in the Ground Vibronic State     Goto   Sponge   NotDistinct   Permalink

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Description
  • Rozšířili jsme měření přechodů v submilimetrové oblasti pro CH2Cl v rozsahu 418 až 470 GHz pro dva izotopy Cl. Radikál byl produkován v rychlém průtočném systému odtržením vodíku z CH3Cl pomocí atomů Cl generovaných v mikrovlnném (2450 MHz) výboji v Cl2 ředěném heliem. Celková analýza (metodou nejmenších čtverců) zahrnující předcházející i nově pozorované přechody vedla k přesnější sestavě rotačních konstant a konstant jemného a hyperjemného štěpení pro dva izotopoméry v jejich základním elektronickém stavu. Navíc jsme také pozorovali CH2Cl při fotolýze (248 nm) CH2BrCl vedoucí k jedno-exponenciální 1/e době života 146 ms. (cs)
  • We have extended the measurement of Submilimeter wave transitions of CH2Cl between 418 and 470 GHz for the two isotopic species of Cl. The radical was produced in a fast flow system by hydrogen abstraction of CH3Cl by Cl atoms obtained from a 2450 MHz microwave discharge in Cl2 diluted with helium. A global least-squares analysis including the previous and the newly observed transitions led to a more precise set of rotational, fine and hyperfine constants for the two isotopomers in their ground vibronic state. In additions, we have also observed CH2Cl by the CH2BrCl, leading to a single 1/e lifetime of 146 ms.
  • We have extended the measurement of Submilimeter wave transitions of CH2Cl between 418 and 470 GHz for the two isotopic species of Cl. The radical was produced in a fast flow system by hydrogen abstraction of CH3Cl by Cl atoms obtained from a 2450 MHz microwave discharge in Cl2 diluted with helium. A global least-squares analysis including the previous and the newly observed transitions led to a more precise set of rotational, fine and hyperfine constants for the two isotopomers in their ground vibronic state. In additions, we have also observed CH2Cl by the CH2BrCl, leading to a single 1/e lifetime of 146 ms. (en)
Title
  • The Submillimeter-wave Spectrum of the Chloromethyl Radical, CH2Cl, in the Ground Vibronic State
  • Sub-milimetrové spektrum chloromethylového radikálu, CH2Cl, v základním vibronickém stavu (cs)
  • The Submillimeter-wave Spectrum of the Chloromethyl Radical, CH2Cl, in the Ground Vibronic State (en)
skos:prefLabel
  • The Submillimeter-wave Spectrum of the Chloromethyl Radical, CH2Cl, in the Ground Vibronic State
  • Sub-milimetrové spektrum chloromethylového radikálu, CH2Cl, v základním vibronickém stavu (cs)
  • The Submillimeter-wave Spectrum of the Chloromethyl Radical, CH2Cl, in the Ground Vibronic State (en)
skos:notation
  • RIV/61388955:_____/05:00000565!RIV06-AV0-61388955
http://linked.open.../vavai/riv/strany
  • 140;144
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IAA1010110), P(IAA3040101), P(OC 723.001), Z(AV0Z40400503)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 545357
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/05:00000565
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • chloromethyl radical; CH2Cl; spectroscopy; milimeter-wave (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [695ECEDE957D]
http://linked.open...i/riv/nazevZdroje
  • Journal of Molecular Spectroscopy
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 229
http://linked.open...iv/tvurceVysledku
  • Zelinger, Zdeněk
  • Bailleux, S.
  • Dréan, P.
  • Godon, M.
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-2852
number of pages
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