| Attributes | Values |
|---|
| rdf:type
| |
| Description
| - Na studium reaktivity stavově vybraných atomárních ionů N+ a O+ byla použita disociativní fotoionizace N2 a O2 pomocí synchrotronního záření v koincidenci s fotoelektrony. Přesný výběr jejich základních stavů N+(3P), O+(4S) nebo excitovaných stavů N+(1D), O+(2D), O+(2P) byl dosáhnutý volbou energie fotonů a následnou diskriminací atomárních iontů s kinetickou energií. Obě studované reakce 15N+ + CD4 a O+ + 13CO2 mají důležitou úlohu v chemických procesech v ionosférách Titánu, Marsu a Venuše a jsou silně závislé na excitaci mateřských iontů. Reakce N+ s metanem vedoucí k produktům DCN+ a DCND+, které pocházejí z rozpadu dlouho žijícího komplexu překvapivě není silně závislá na exitaci N+.Oproti tomu disociativní přenos náboje vedoucí k CD3+ je dominantní pro reakci s N+ v základním stavu a nedisociativní přenos náboje vedoucí k CD4+ převažuje v případě, kdy N+ je v excitovaném 1D stavu. Tento neočakávaný výsledek může být vysvětlitelný pomocí spin-orbitových výběrových pravidel ... (cs)
- The dissociative photoionization of N-2 and O-2 by synchrotron radiation in coincidence with threshold photoelectrons is used to produce state-selected N+ and O+ atomic ions to study their reactivity. A pure selection of their ground state, N+(P-3) and O+(S-4), or excited states, N+(D-1), O+(D-2), and O+(P-2), is obtained by the choice of the photon energy and by further discrimination of atomic ions produced with translational recoil energy. Both reactions studied, N-15(+) + CD4 and O+ + (CO2)-C-13, are of major importance for the chemistry of Titan, Mars, and Venus´ionospheres and are strongly affected by excitation of the parent atomic ion. For the reaction of N+ with methane, DCN+ and DCND+ products coming from the decomposition of a long-lived complex are surprisingly not much sensitive to the N+ excitation, whereas the branching ratio between the dissociative charge-transfer channel, leading to CD3+, which is the main product for the ground-state reaction.
- The dissociative photoionization of N-2 and O-2 by synchrotron radiation in coincidence with threshold photoelectrons is used to produce state-selected N+ and O+ atomic ions to study their reactivity. A pure selection of their ground state, N+(P-3) and O+(S-4), or excited states, N+(D-1), O+(D-2), and O+(P-2), is obtained by the choice of the photon energy and by further discrimination of atomic ions produced with translational recoil energy. Both reactions studied, N-15(+) + CD4 and O+ + (CO2)-C-13, are of major importance for the chemistry of Titan, Mars, and Venus´ionospheres and are strongly affected by excitation of the parent atomic ion. For the reaction of N+ with methane, DCN+ and DCND+ products coming from the decomposition of a long-lived complex are surprisingly not much sensitive to the N+ excitation, whereas the branching ratio between the dissociative charge-transfer channel, leading to CD3+, which is the main product for the ground-state reaction. (en)
|
| Title
| - 15N+ +CD4 and O+ +-13CO2 State-Selected Ion-Molecule Reactions Relevant to the Chemistry of Planetary Ionospheres
- 15N+ +CD4 and O+ +-13CO2 State-Selected Ion-Molecule Reactions Relevant to the Chemistry of Planetary Ionospheres (en)
- Stavově vybrané ión-molekulové reakce 15N+ + CD4 a O+ + 13CO2 důležité v chemii ionosféry planet (cs)
|
| skos:prefLabel
| - 15N+ +CD4 and O+ +-13CO2 State-Selected Ion-Molecule Reactions Relevant to the Chemistry of Planetary Ionospheres
- 15N+ +CD4 and O+ +-13CO2 State-Selected Ion-Molecule Reactions Relevant to the Chemistry of Planetary Ionospheres (en)
- Stavově vybrané ión-molekulové reakce 15N+ + CD4 a O+ + 13CO2 důležité v chemii ionosféry planet (cs)
|
| skos:notation
| - RIV/61388955:_____/04:00107670!RIV/2005/AV0/A54005/N
|
| http://linked.open.../vavai/riv/strany
| |
| http://linked.open...avai/riv/aktivita
| |
| http://linked.open...avai/riv/aktivity
| - P(IAA4040405), Z(AV0Z4040901)
|
| http://linked.open...iv/cisloPeriodika
| |
| http://linked.open...vai/riv/dodaniDat
| |
| http://linked.open...aciTvurceVysledku
| |
| http://linked.open.../riv/druhVysledku
| |
| http://linked.open...iv/duvernostUdaju
| |
| http://linked.open...titaPredkladatele
| |
| http://linked.open...dnocenehoVysledku
| |
| http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/04:00107670
|
| http://linked.open...riv/jazykVysledku
| |
| http://linked.open.../riv/klicovaSlova
| - charge-transfer reactions; cross-sections; kinetic energy (en)
|
| http://linked.open.../riv/klicoveSlovo
| |
| http://linked.open...odStatuVydavatele
| - US - Spojené státy americké
|
| http://linked.open...ontrolniKodProRIV
| |
| http://linked.open...i/riv/nazevZdroje
| - Journal of Physical Chemistry
|
| http://linked.open...in/vavai/riv/obor
| |
| http://linked.open...ichTvurcuVysledku
| |
| http://linked.open...cetTvurcuVysledku
| |
| http://linked.open...vavai/riv/projekt
| |
| http://linked.open...UplatneniVysledku
| |
| http://linked.open...v/svazekPeriodika
| |
| http://linked.open...iv/tvurceVysledku
| - Žabka, Ján
- Alcaraz, Ch.
- Dutuit, O.
- Thissen, R.
- Nicolas, Ch.
|
| http://linked.open...n/vavai/riv/zamer
| |
| issn
| |
| number of pages
| |
![[RDF Data]](/fct/images/sw-rdf-blue.png)
![[cxml]](/fct/images/cxml_doc.png)
![[csv]](/fct/images/csv_doc.png)
![[text]](/fct/images/ntriples_doc.png)
![[turtle]](/fct/images/n3turtle_doc.png)
![[ld+json]](/fct/images/jsonld_doc.png)
![[rdf+json]](/fct/images/json_doc.png)
![[rdf+xml]](/fct/images/xml_doc.png)
![[atom+xml]](/fct/images/atom_doc.png)
![[html]](/fct/images/html_doc.png)