About: Synthesis and Structure of Bis {.eta.5-1, 2, 3, 4-tetramethyl-5-(dimethylsilylsulfido-kS) cyclopetadienyl}titanium(IV)

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: Synthesis and Structure of Bis {.eta.5-1, 2, 3, 4-tetramethyl-5-(dimethylsilylsulfido-kS) cyclopetadienyl}titanium(IV) Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Bis{?5-(N,N-dimethylaminodimethylsilyl) tetramethylcyklopentadienyl}dichlorotitan(IV), [TiCl2{?5-C5Me4(SiMe2NMe2)}2] (1), reaguje se sulfanem štěpením obou Si-N a Ti-Cl vazeb za vzniku sulfido-vázané titanocenové sloučeniny bis{?5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-?S) cyklopentadienyl}titan(IV), [Ti{?5-C5Me4(SiMe2S-?S)}2] (4), a dimethylamin hydrochloridu jako vedlejšího produktu. Krystalová struktura 4 byla určena rentgenostrukturní analýzou. (cs) Bis{.eta.5-(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV), [TiCl2{.eta.5-C5Me4(SiMe2NMe2)}2] (1), reacts with sulfane under cleavage of both Si-N and Ti-Cl bonds to give sulfido-tethered titanocene compound bis{.eta.5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-.kappa.S)cyclopentadienyl}titanium(IV), [Ti{.eta.5-C5Me4(SiMe2S-.kappa.S)}2] (4), and dimethylamine hydrochloride as the byproduct. The crystal structure of compound 4 has been determined by single-crystal X-ray diffraction. Bis{.eta.5-(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV), [TiCl2{.eta.5-C5Me4(SiMe2NMe2)}2] (1), reacts with sulfane under cleavage of both Si-N and Ti-Cl bonds to give sulfido-tethered titanocene compound bis{.eta.5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-.kappa.S)cyclopentadienyl}titanium(IV), [Ti{.eta.5-C5Me4(SiMe2S-.kappa.S)}2] (4), and dimethylamine hydrochloride as the byproduct. The crystal structure of compound 4 has been determined by single-crystal X-ray diffraction. (en)
Title	Synthesis and Structure of Bis {.eta.5-1, 2, 3, 4-tetramethyl-5-(dimethylsilylsulfido-kS) cyclopetadienyl}titanium(IV) Syntéza a struktura bis{?5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-?S) cyklopentadienyl}titanového(IV) komplexu (cs) Synthesis and Structure of Bis {.eta.5-1, 2, 3, 4-tetramethyl-5-(dimethylsilylsulfido-kS) cyclopetadienyl}titanium(IV) (en)
skos:prefLabel	Synthesis and Structure of Bis {.eta.5-1, 2, 3, 4-tetramethyl-5-(dimethylsilylsulfido-kS) cyclopetadienyl}titanium(IV) Syntéza a struktura bis{?5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-?S) cyklopentadienyl}titanového(IV) komplexu (cs) Synthesis and Structure of Bis {.eta.5-1, 2, 3, 4-tetramethyl-5-(dimethylsilylsulfido-kS) cyclopetadienyl}titanium(IV) (en)
skos:notation	RIV/61388955:_____/04:00107575!RIV/2005/AV0/A54005/N
http://linked.open.../vavai/riv/strany	1135;1138
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/02/0774), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	-
http://linked.open...vai/riv/dodaniDat	2005
http://linked.open...aciTvurceVysledku	Horáček, Michal Mach, Karel Kubišta, Jiří Pinkas, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	589334
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/04:00107575
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	titanium; titanocene; pendant amino group (en)
http://linked.open.../riv/klicoveSlovo	titanium titanocene pendant amino group
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[9718DF55FD52]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor	BM
http://linked.open...ichTvurcuVysledku	4 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...vavai/riv/projekt	Silicon-based ansa-titanocene complexes - synthesis, properties and catalytic activities
http://linked.open...UplatneniVysledku	2004
http://linked.open...v/svazekPeriodika	7
http://linked.open...iv/tvurceVysledku	Mach, Karel Pinkas, Jiří Štěpnička, P. Gyepes, R. Horáček, Michal Kubišta, Jiří
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	1387-7003
number of pages	4 (xsd:int)

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software