About: Time-resolved Fourier Transform Infrared Emmision Spectroscopy of He2 Produced by a Pulsed Discharge

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Časově rozlišená Fourier transform spektroskopie byla aplikována při studiu He2 infračervené emise pomocí pulzního výboje v čistém He. V oblasti 1800-8000 cm-1 byly pozorovány nové elektronické pásy. Z pozorovaných časových profilů emisních spekter byly identifikovány Rydbergovy stavy s vyšší energií než b3? stav. Byla provedeno rotační přiřazení a analýza pomocí nejmenších čtverců h3.SIGMA.? - g3.SIGMA. a g3.SIGMA.-d3.SIGMA. pásů v oblasti 3200 cm-1. Zároveň byly určeny molekulární parametry. Nový pás s nepravidelnou strukturou intensit P a R větví byl identifikován v oblasti 6300 cm-1. (cs) Time-resolved Fourier transform spectroscopy was applied to the study of He-2 infrared emission produced by a pulsed discharge in pure He. In the 1800-8000 cm(-1) region, new electronic bands have been observed in addition to the previously reported transitions. From the observed time profiles of emission spectra, Rydberg states with higher energy than the b(3)Pi state produced efficiently in afterglow plasma have been identified. Rotational assignments and a least-squares analysis for the h(3)Sigma(u)(+)-g(3)Sigma(g)(+) and g(3)Sigma(g)(+)-d(3)Sigma(u)(+) bands in the 3200 cm(-1) region were carried out to determine the molecular constants. A new band from an unidentified g U state to the d(3)Sigma(u)(+) state has been observed in the 6300 cm(-1) region with irregular P- and R-branch intensities. Time-resolved Fourier transform spectroscopy was applied to the study of He-2 infrared emission produced by a pulsed discharge in pure He. In the 1800-8000 cm(-1) region, new electronic bands have been observed in addition to the previously reported transitions. From the observed time profiles of emission spectra, Rydberg states with higher energy than the b(3)Pi state produced efficiently in afterglow plasma have been identified. Rotational assignments and a least-squares analysis for the h(3)Sigma(u)(+)-g(3)Sigma(g)(+) and g(3)Sigma(g)(+)-d(3)Sigma(u)(+) bands in the 3200 cm(-1) region were carried out to determine the molecular constants. A new band from an unidentified g U state to the d(3)Sigma(u)(+) state has been observed in the 6300 cm(-1) region with irregular P- and R-branch intensities. (en)
Title	Time-resolved Fourier Transform Infrared Emmision Spectroscopy of He2 Produced by a Pulsed Discharge Time-resolved Fourier Transform Infrared Emmision Spectroscopy of He2 Produced by a Pulsed Discharge (en) Časově rozlišená Fourier transform infračervená emisní spektroskopie He2 produkovaného pulzním výbojem (cs)
skos:prefLabel	Time-resolved Fourier Transform Infrared Emmision Spectroscopy of He2 Produced by a Pulsed Discharge Time-resolved Fourier Transform Infrared Emmision Spectroscopy of He2 Produced by a Pulsed Discharge (en) Časově rozlišená Fourier transform infračervená emisní spektroskopie He2 produkovaného pulzním výbojem (cs)
skos:notation	RIV/61388955:_____/04:00101125!RIV/2005/AV0/A54005/N
http://linked.open.../vavai/riv/strany	256;260
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/01/0618), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	3/4
http://linked.open...vai/riv/dodaniDat	2005
http://linked.open...aciTvurceVysledku	Civiš, Svatopluk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	590374
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/04:00101125
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	multichannel; hydrogen; interactions (en)
http://linked.open.../riv/klicoveSlovo	hydrogen interactions multichannel
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[41AA8033B773]
http://linked.open...i/riv/nazevZdroje	Chemical Physics Letters
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	3 (xsd:int)
http://linked.open...vavai/riv/projekt	Dynamics and structure of small ionic clusters studied by high resolution spectroscopy
http://linked.open...UplatneniVysledku	2004
http://linked.open...v/svazekPeriodika	383
http://linked.open...iv/tvurceVysledku	Civiš, Svatopluk Kawaguchi, K. Hosaki, Y.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0009-2614
number of pages	5 (xsd:int)

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