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  • Byla popsána referentní nasycená kalomelová elektroda využívající netoxického pevného stříbrného amalgamu (SCE-AgSA) místo kapalné rtuti. Dlouhodobé i krátkodobé testy provedené během období jednoho roku potvrdily, že potenciál SCE-AgSA je shodný s potenciálem SCE (rozdíl ?ESCE-AgSA = +1,08 ? 0,24 mV vs. SCE; SD = 0,87; N = 51). Voltamogramy čtyř vybraných kovových iontů registrované vs. SCE-AgSA a vs. SCE byly jeden přes druhý překryty. Žádná z uvedených elektrod nepodléhala znatelné polarizaci, ani při průchodu proudu 2 mA. Na základě získaných výsledků může být SCE-AgSA považována za ekvivalent SCE. Kvůli prakticky identickým elektrodovým potenciálům obou typů zmíněných elektrod jsou výsledky s použitím SCE-AgSA zcela srovnatelné s výsledky měření vs. SCE, bez jakýchkoliv korekcí hodnot potenciálů píků. (cs)
  • A reference saturated calomel electrode based on the non-toxic silver solid amalgam (SCE-AgSA) as a substitute for liquid mercury is described. Long-term as well as short-term tests made during a period of one year confirmed the SCE-AgSA potential to be equal to that of SCE within the limits of +/-1 mV (the difference DeltaE(SCE-AgSA) = + 1.08 +/- 0.24 mV (vs. SCE); SD = 0.87; N = 5 1). The voltammograms of four selected metal ions registered vs. SCE-AgSA and vs. SCE could practically overlap each other. None of the mentioned electrodes were polarized to a significant degree even if the electric current applied reached 2 mA. On the basis of the obtained results the SCE-AgSA could be considered as equivalent substitute for SCE. Owing to practically identical electrode potential of both types of the mentioned electrodes the results obtained using SCF-AgSA are completely comparable to those measured vs. SCE, without any correction of peak potentials.
  • A reference saturated calomel electrode based on the non-toxic silver solid amalgam (SCE-AgSA) as a substitute for liquid mercury is described. Long-term as well as short-term tests made during a period of one year confirmed the SCE-AgSA potential to be equal to that of SCE within the limits of +/-1 mV (the difference DeltaE(SCE-AgSA) = + 1.08 +/- 0.24 mV (vs. SCE); SD = 0.87; N = 5 1). The voltammograms of four selected metal ions registered vs. SCE-AgSA and vs. SCE could practically overlap each other. None of the mentioned electrodes were polarized to a significant degree even if the electric current applied reached 2 mA. On the basis of the obtained results the SCE-AgSA could be considered as equivalent substitute for SCE. Owing to practically identical electrode potential of both types of the mentioned electrodes the results obtained using SCF-AgSA are completely comparable to those measured vs. SCE, without any correction of peak potentials. (en)
Title
  • Reference Electrodes Based on Solid Amalgams
  • Reference Electrodes Based on Solid Amalgams (en)
  • Referentní elektrody založené na pevných amalgamech (cs)
skos:prefLabel
  • Reference Electrodes Based on Solid Amalgams
  • Reference Electrodes Based on Solid Amalgams (en)
  • Referentní elektrody založené na pevných amalgamech (cs)
skos:notation
  • RIV/61388955:_____/04:00101042!RIV/2005/AV0/A54005/N
http://linked.open.../vavai/riv/strany
  • 238;241
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(OE92), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • 3
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 583944
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/04:00101042
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • solid amalgam; reference electrode; voltammetry (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [22FBACE29374]
http://linked.open...i/riv/nazevZdroje
  • Electroanalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 16
http://linked.open...iv/tvurceVysledku
  • Novotný, Ladislav
  • Yosypchuk, Bogdan
http://linked.open...n/vavai/riv/zamer
issn
  • 1040-0397
number of pages
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