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  • Voltametricky byla studována Fentonova reakce na rozhraní voda / 1,2-dichloroethan s peroxidem vodíku ve vodné fázi a (ferocenylmethyl)trimethylamonium (TMFe+) kationtem v organické fázi. Byl ověřen reakční mechanismus a stanovena reakční kinetika. Bylo ukázáno, že tento systém může sloužit pro řízenou přípravu OH. radikálů, kterých lze zřejmě využít k iniciaci polymerace vhodných monomerů adsorbovaných na rozhraní. (cs)
  • The Fenton reaction was studied voltammetrically at a water/1,2-dichloroethane interface, with hydrogen peroxide in the aqueous phase and (ferrocenylmethyl)trimethylammonium cation (TMFc+) in the organic phase. The reaction mechanism was verified and the reaction kinetics established. It has been shown that this system can be used for controlled production of OHÓ radicals that can possibly be applied to initiating polymerization of suitable monomers adsorbed at the interface.
  • The Fenton reaction was studied voltammetrically at a water/1,2-dichloroethane interface, with hydrogen peroxide in the aqueous phase and (ferrocenylmethyl)trimethylammonium cation (TMFc+) in the organic phase. The reaction mechanism was verified and the reaction kinetics established. It has been shown that this system can be used for controlled production of OHÓ radicals that can possibly be applied to initiating polymerization of suitable monomers adsorbed at the interface. (en)
Title
  • The Potential Controlled Fenton Reaction at Liquid/Liquid Interfaces as the Source of Hydroxyl Radicals
  • Potenciálem řízená Fentonova reakce na kapalném rozhraní jako zdroj hydroxylových radikálů (cs)
  • The Potential Controlled Fenton Reaction at Liquid/Liquid Interfaces as the Source of Hydroxyl Radicals (en)
skos:prefLabel
  • The Potential Controlled Fenton Reaction at Liquid/Liquid Interfaces as the Source of Hydroxyl Radicals
  • Potenciálem řízená Fentonova reakce na kapalném rozhraní jako zdroj hydroxylových radikálů (cs)
  • The Potential Controlled Fenton Reaction at Liquid/Liquid Interfaces as the Source of Hydroxyl Radicals (en)
skos:notation
  • RIV/61388955:_____/04:00101021!RIV/2005/AV0/A54005/N
http://linked.open.../vavai/riv/strany
  • 277;281
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(ME 510), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • 1/2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 580754
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/04:00101021
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • liquid/liquid interfaces; homogeneous reaction; Fenton reaction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [FB1B4553B43B]
http://linked.open...i/riv/nazevZdroje
  • Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 563
http://linked.open...iv/tvurceVysledku
  • Mareček, Vladimír
  • Štulík, K.
  • Brusová, Z.
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-0728
number of pages
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