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rdf:type
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Description
| - 2-Ferrocenylmethyl)amino-2-methylpropan-1-ol (1) was synthesized and converted to the respective ammonium bromide ([1H]Br = 2) and dihydrogenphosphate ([1H]H2PO4 = 3). The solid-state structures of 1, 2 and the solvated salt 3 . 1/6 Et2O (3a) have been determined by X-ray diffraction. The solid-state assemblies of 1 and 2 are dominated by infinite ladder-like arrays interconnected by hydrogen bonds whereas the solid-state structure of 3a is built up from linear hydrogen-bonded dihydrogenphosphate chains, which are interlinked via hydrogen bonds to the cation [1H]+ into a complicated three-dimensional network. Compound 1 and its interactions with Bu4NBr and Bu4NH2PO4 in solution were further studied by electrochemical methods and NMR titrations.
- 2-Ferrocenylmethyl)amino-2-methylpropan-1-ol (1) was synthesized and converted to the respective ammonium bromide ([1H]Br = 2) and dihydrogenphosphate ([1H]H2PO4 = 3). The solid-state structures of 1, 2 and the solvated salt 3 . 1/6 Et2O (3a) have been determined by X-ray diffraction. The solid-state assemblies of 1 and 2 are dominated by infinite ladder-like arrays interconnected by hydrogen bonds whereas the solid-state structure of 3a is built up from linear hydrogen-bonded dihydrogenphosphate chains, which are interlinked via hydrogen bonds to the cation [1H]+ into a complicated three-dimensional network. Compound 1 and its interactions with Bu4NBr and Bu4NH2PO4 in solution were further studied by electrochemical methods and NMR titrations. (en)
- 2-Ferrocenylmethyl)amino-2-methylpropan-1-ol (1) byl připraven a převeden na příslušný amoniový bromid (2) a dihydrogenfosforečnan (3). Krystalová struktura ukázala, že v případě 1 a 2 převládá uspořádání podobné nekonečným žebříkům propojeným vodíkovými můstky, zatímco struktura 3 je tvořena lineárními řetězci propojenými do složitého trojrozměrného seskupení. Látky a jejich interakce se základním elektrolytem byly dále studovány elektrochemicky a pomocí NMR titrací. (cs)
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Title
| - Acid-base and Counter Ion Dependent Solid-state Assembly of a Ferrocene Beta-aminoalcohol and the Corresponding Ammonium Salt
- Ferrocen-Beta-aminoalkohol a jeho amoniová sůl: uspořádání molekul v pevné fázi závislé na povaze aniontů základního elektrolytu a na acidobazických podmínkách (cs)
- Acid-base and Counter Ion Dependent Solid-state Assembly of a Ferrocene Beta-aminoalcohol and the Corresponding Ammonium Salt (en)
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skos:prefLabel
| - Acid-base and Counter Ion Dependent Solid-state Assembly of a Ferrocene Beta-aminoalcohol and the Corresponding Ammonium Salt
- Ferrocen-Beta-aminoalkohol a jeho amoniová sůl: uspořádání molekul v pevné fázi závislé na povaze aniontů základního elektrolytu a na acidobazických podmínkách (cs)
- Acid-base and Counter Ion Dependent Solid-state Assembly of a Ferrocene Beta-aminoalcohol and the Corresponding Ammonium Salt (en)
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skos:notation
| - RIV/61388955:_____/04:00101016!RIV/2005/AV0/A54005/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(GA203/99/M037), P(GP203/01/P002), Z(AV0Z4040901), Z(MSM 113100001)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/04:00101016
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - ferrocene; aminoalcohols; hydrogen bonding (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - CH - Švýcarská konfederace
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Journal of Organometallic Chemistry
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Císařová, I.
- Štěpnička, P.
- Ludvík, Jiří
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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