About: Polymerizations Catalyzed with Rhodium Complexes.

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An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	In the last decade, rhodium complexes are increasingly used as catalysts for a preparation of specialty polymers of diverse functionality, since a use of them brings about important advantages. Rh-catalysts (i) show unusually high tolerance to the reaction surroundings as well as to functional groups of reactants and products, (ii) they often show a precise control of the configurational structure of formed macromolecules (particularly those of polyvinylenes), (iii) they can be transformed to the living polymerization systems, (iv) they can be anchored on various inorganic and organic supports to give effective heterogeneous catalysts, and (v) they can catalyze reactions in the ionic liquid systems. Rhodium complexes are prevailingly used for a preparation of stereoregular (head-to-tail, cis-transoid) polymers of monosubstituted acetylenes, molecules of which easily adopt the helical conformation in the solid state, some of them even in solutions (e.g., molecules of poly(propiolate)s). In the last decade, rhodium complexes are increasingly used as catalysts for a preparation of specialty polymers of diverse functionality, since a use of them brings about important advantages. Rh-catalysts (i) show unusually high tolerance to the reaction surroundings as well as to functional groups of reactants and products, (ii) they often show a precise control of the configurational structure of formed macromolecules (particularly those of polyvinylenes), (iii) they can be transformed to the living polymerization systems, (iv) they can be anchored on various inorganic and organic supports to give effective heterogeneous catalysts, and (v) they can catalyze reactions in the ionic liquid systems. Rhodium complexes are prevailingly used for a preparation of stereoregular (head-to-tail, cis-transoid) polymers of monosubstituted acetylenes, molecules of which easily adopt the helical conformation in the solid state, some of them even in solutions (e.g., molecules of poly(propiolate)s). (en)
Title	Polymerizations Catalyzed with Rhodium Complexes. Polymerizations Catalyzed with Rhodium Complexes. (en)
skos:prefLabel	Polymerizations Catalyzed with Rhodium Complexes. Polymerizations Catalyzed with Rhodium Complexes. (en)
skos:notation	RIV/61388955:_____/03:54030268!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	131;154
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/02/0976), P(GA203/03/0281), Z(AV0Z4040901)
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Balcar, Hynek
http://linked.open.../riv/druhVysledku	C - Kapitola v knize
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	621530
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030268
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	rhodium complexes; polymerizations (en)
http://linked.open.../riv/klicoveSlovo	rhodium complexes polymerizations
http://linked.open...ontrolniKodProRIV	[BD46CBAEEEAA]
http://linked.open...i/riv/mistoVydani	Dordrecht
http://linked.open...vEdiceCisloSvazku	NATO Science Series.
http://linked.open...i/riv/nazevZdroje	Novel Metathesis Chemistry: Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Material Applications.
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	New Catalysts for the Atom Transfer Radical Polymerization Mesoporous molecular sieves immobilized catalysts for olefin metathesis and related polymerizations
http://linked.open...UplatneniVysledku	2003
http://linked.open...iv/tvurceVysledku	Sedláček, J. Balcar, Hynek Svoboda, J. Vohlídal, J. Pacovská, M. Zedník, J.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
number of pages	24 (xsd:int)
http://purl.org/ne...btex#hasPublisher	Kluwer Academic
https://schema.org/isbn	1-4020-1571-2

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