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  • A selected ion flow tube, SIFT, study has been carried out of the reactions of hydrated nitrosonium ions, NO+H2O, which theory has equated to protonated nitrous acid ions, H2ONO+. A major objective of this study was to investigate if this ion exhibits the properties of both a cluster ion and a protonated acid in their reactions with a variety of organic molecules. The chosen reactant molecules comprise two each of the following types ů amines, terpenes, aromatic hydrocarbons, esters, carboxylic acids, ketones, aldehydes and alcohols. The reactant H2ONO+ (NO+H2O) ions are formed in a discharge ion source and injected into helium carrier gas where they are partially vibrationally excited and partially dissociated to NO+ ions. Hence, the reactions of the H2ONO+ ions had to be studies simultaneously with NO+ ions, the reactions of the latter ions readily being studied by selectively injecting NO+ ions into the carrier gas. The results of this study indicate that the H2ONO+ ions undergo.
  • A selected ion flow tube, SIFT, study has been carried out of the reactions of hydrated nitrosonium ions, NO+H2O, which theory has equated to protonated nitrous acid ions, H2ONO+. A major objective of this study was to investigate if this ion exhibits the properties of both a cluster ion and a protonated acid in their reactions with a variety of organic molecules. The chosen reactant molecules comprise two each of the following types ů amines, terpenes, aromatic hydrocarbons, esters, carboxylic acids, ketones, aldehydes and alcohols. The reactant H2ONO+ (NO+H2O) ions are formed in a discharge ion source and injected into helium carrier gas where they are partially vibrationally excited and partially dissociated to NO+ ions. Hence, the reactions of the H2ONO+ ions had to be studies simultaneously with NO+ ions, the reactions of the latter ions readily being studied by selectively injecting NO+ ions into the carrier gas. The results of this study indicate that the H2ONO+ ions undergo. (en)
Title
  • A SIFT Study of the Reactions of H2ONO+ Ions with Several Types of Organic Molecules.
  • A SIFT Study of the Reactions of H2ONO+ Ions with Several Types of Organic Molecules. (en)
skos:prefLabel
  • A SIFT Study of the Reactions of H2ONO+ Ions with Several Types of Organic Molecules.
  • A SIFT Study of the Reactions of H2ONO+ Ions with Several Types of Organic Molecules. (en)
skos:notation
  • RIV/61388955:_____/03:54030264!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany
  • 1;9
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/03/0827), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • 1
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 597137
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/03:54030264
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • SIFT; nitrosohydronium ions; protonated nitrous acid (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [2B23BFA73134]
http://linked.open...i/riv/nazevZdroje
  • International Journal of Mass Spectrometry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 230
http://linked.open...iv/tvurceVysledku
  • Smith, D.
  • Španěl, Patrik
  • Wang, T.
http://linked.open...n/vavai/riv/zamer
issn
  • 1387-3806
number of pages
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