About: Study of the Complexation, Adsorption and of the Electrode Reaction Mechanisms of Chromium(VI) and (III) with DTPA Under Adsorptive Stripping Voltammetric Conditions.     Goto   Sponge   NotDistinct   Permalink

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  • The complexation of Cr(III) and Cr(VI) with diethylenetriaminepentaacetic acid (DTPA), the redox behavior of these complexes and their adsorption on the mercury electrode surface were investigated by a combination of electrochemical techniques and UV/vis spectroscopy. A homogeneous two-step reaction was observed when mixing Cr(III), present as hexaquo complex, with DTPA. The first reaction product, the electroactive 1:1 complex, turns into an electroinactive form in the second step. the results indicate that the second reaction product is presumably a 1:2 Cr(III)/DTPA complex.
  • The complexation of Cr(III) and Cr(VI) with diethylenetriaminepentaacetic acid (DTPA), the redox behavior of these complexes and their adsorption on the mercury electrode surface were investigated by a combination of electrochemical techniques and UV/vis spectroscopy. A homogeneous two-step reaction was observed when mixing Cr(III), present as hexaquo complex, with DTPA. The first reaction product, the electroactive 1:1 complex, turns into an electroinactive form in the second step. the results indicate that the second reaction product is presumably a 1:2 Cr(III)/DTPA complex. (en)
Title
  • Study of the Complexation, Adsorption and of the Electrode Reaction Mechanisms of Chromium(VI) and (III) with DTPA Under Adsorptive Stripping Voltammetric Conditions.
  • Study of the Complexation, Adsorption and of the Electrode Reaction Mechanisms of Chromium(VI) and (III) with DTPA Under Adsorptive Stripping Voltammetric Conditions. (en)
skos:prefLabel
  • Study of the Complexation, Adsorption and of the Electrode Reaction Mechanisms of Chromium(VI) and (III) with DTPA Under Adsorptive Stripping Voltammetric Conditions.
  • Study of the Complexation, Adsorption and of the Electrode Reaction Mechanisms of Chromium(VI) and (III) with DTPA Under Adsorptive Stripping Voltammetric Conditions. (en)
skos:notation
  • RIV/61388955:_____/03:54030192!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany
  • 1513;1521
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • 19
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 629603
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/03:54030192
http://linked.open...riv/jazykVysledku
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  • chromium(VI) and (III); voltammetry; complexation with DTPA (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • DE - Spolková republika Německo
http://linked.open...ontrolniKodProRIV
  • [9326C845B4BB]
http://linked.open...i/riv/nazevZdroje
  • Electroanalysis
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 15
http://linked.open...iv/tvurceVysledku
  • Navrátil, Tomáš
  • Novotný, Ladislav
  • Sander, S.
http://linked.open...n/vavai/riv/zamer
issn
  • 1040-0397
number of pages
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