About: Electrochemically Controlled Formation of a Silicate Membrane at a Liquit/Liquit Interface.     Goto   Sponge   NotDistinct   Permalink

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Description
  • A new method is described for preparation of a silicate membrane. Its principal idea lies in the separation of the template and precursor ions participating in sol-gel processes, by the interface between two immiscible electrolyte solutions (ITIES). The sol-gel process is initiated by potential-controlled adsorption of the template ions at the interface and their transfer from the organic to the aqueous phase. Association of the positive template ions with the silicate ions at the aqueous side of the interface produces neutral species which condensate and form a compact layer at the interface. The thickness of the layer can be controlled by the magnitude of the electrical charge passed.
  • A new method is described for preparation of a silicate membrane. Its principal idea lies in the separation of the template and precursor ions participating in sol-gel processes, by the interface between two immiscible electrolyte solutions (ITIES). The sol-gel process is initiated by potential-controlled adsorption of the template ions at the interface and their transfer from the organic to the aqueous phase. Association of the positive template ions with the silicate ions at the aqueous side of the interface produces neutral species which condensate and form a compact layer at the interface. The thickness of the layer can be controlled by the magnitude of the electrical charge passed. (en)
Title
  • Electrochemically Controlled Formation of a Silicate Membrane at a Liquit/Liquit Interface.
  • Electrochemically Controlled Formation of a Silicate Membrane at a Liquit/Liquit Interface. (en)
skos:prefLabel
  • Electrochemically Controlled Formation of a Silicate Membrane at a Liquit/Liquit Interface.
  • Electrochemically Controlled Formation of a Silicate Membrane at a Liquit/Liquit Interface. (en)
skos:notation
  • RIV/61388955:_____/03:54030157!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany
  • 119;123
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/03/0822), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • 1/2
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 605632
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/03:54030157
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • immiscible electrolyte solutions; sol-gel; silicalite layer (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV
  • [8EF477702AC3]
http://linked.open...i/riv/nazevZdroje
  • Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 558 C
http://linked.open...iv/tvurceVysledku
  • Mareček, Vladimír
  • Jänchenová, Hana
http://linked.open...n/vavai/riv/zamer
issn
  • 0022-0728
number of pages
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