About: Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide.     Goto   Sponge   NotDistinct   Permalink

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  • Thermally programmed desorption technique has been applied to the investigation of 'virgin' and repeated adsorption of carbon monoxide on Pd/Nb and Pd/Nb2O5/Nb systems. The desorbed products of the CO interaction with these surfaces, namely, CO and CO2 molecules were monitored by a quadrupole mass spectrometer. On the basis of presented results some of the observed differences between the metal- and oxide-supported active metal (Pd) have been ascribed to the morphological rather than to chemical (electronic) effects in these systems. The different excess kinetic energy dissipation of Pd atoms colliding with metallic or oxidic surface is considered to influence the initial growth of the Pd layer, resulting afterwards in a different morphology of the final Pd layers.
  • Thermally programmed desorption technique has been applied to the investigation of 'virgin' and repeated adsorption of carbon monoxide on Pd/Nb and Pd/Nb2O5/Nb systems. The desorbed products of the CO interaction with these surfaces, namely, CO and CO2 molecules were monitored by a quadrupole mass spectrometer. On the basis of presented results some of the observed differences between the metal- and oxide-supported active metal (Pd) have been ascribed to the morphological rather than to chemical (electronic) effects in these systems. The different excess kinetic energy dissipation of Pd atoms colliding with metallic or oxidic surface is considered to influence the initial growth of the Pd layer, resulting afterwards in a different morphology of the final Pd layers. (en)
Title
  • Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide.
  • Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide. (en)
skos:prefLabel
  • Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide.
  • Carbon Monoxide Chemisorption and Disproportionation on Thin Palladium Layers, Supported by Niobium and Niobium Pentoxide. (en)
skos:notation
  • RIV/61388955:_____/03:54030155!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany
  • 1833;1847
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA202/02/0618), P(GV202/98/K002), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • 10
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
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http://linked.open...dnocenehoVysledku
  • 600351
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/03:54030155
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • thermally programmed desorption; energy dissipation; carbon monoxide (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • CZ - Česká republika
http://linked.open...ontrolniKodProRIV
  • [C4D3DE195D4B]
http://linked.open...i/riv/nazevZdroje
  • Collection of Czechoslovak Chemical Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 68
http://linked.open...iv/tvurceVysledku
  • Plšek, Jan
  • Thiam, Michel Malick
  • Knor, Zlatko
  • Nikolajenko, Vladimír
http://linked.open...n/vavai/riv/zamer
issn
  • 0010-0765
number of pages
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