About: The Use of Limiting Currents in Determination of the Effect of Viscosity in Electrochemical Experiments Performed in Mixtures of Water with Some Organic Co-Solvents.

Facets (new session)
Description
Metadata
Settings
- owl:sameAs
- Inference Rule:

About: The Use of Limiting Currents in Determination of the Effect of Viscosity in Electrochemical Experiments Performed in Mixtures of Water with Some Organic Co-Solvents. Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Ratios of limiting diffusion controlled currents recorded in aqueous solutions to those obtained in mixture with water-soluble organic co-solvents yield values of rel1/2. These values can be used for evaluation of electrochemical experiments in such media and for distinguishing currents affected solely by a change in viscosity from those caused by other solvent-solute interactions, e.g. covalent additions. Limiting currents of Cd2+ ions and of 2-hydroxy-1,4-naphthoquinone proved to yield most reliable result, values of rel1/2 obtained with Tl+ ions showed somewhat poorer correlation. The average values of rel1/2 obtained from comparison of limiting currents for mixtures of water with ethanol and acetonitrile are in very good agreement with average values of rel1/2 reported in the literature and in acceptable agreement for mixtures of water with 2-propanol. Nevertheless, the electrochemical data show much smaller standard deviations. Ratios of limiting diffusion controlled currents recorded in aqueous solutions to those obtained in mixture with water-soluble organic co-solvents yield values of rel1/2. These values can be used for evaluation of electrochemical experiments in such media and for distinguishing currents affected solely by a change in viscosity from those caused by other solvent-solute interactions, e.g. covalent additions. Limiting currents of Cd2+ ions and of 2-hydroxy-1,4-naphthoquinone proved to yield most reliable result, values of rel1/2 obtained with Tl+ ions showed somewhat poorer correlation. The average values of rel1/2 obtained from comparison of limiting currents for mixtures of water with ethanol and acetonitrile are in very good agreement with average values of rel1/2 reported in the literature and in acceptable agreement for mixtures of water with 2-propanol. Nevertheless, the electrochemical data show much smaller standard deviations. (en)
Title	The Use of Limiting Currents in Determination of the Effect of Viscosity in Electrochemical Experiments Performed in Mixtures of Water with Some Organic Co-Solvents. The Use of Limiting Currents in Determination of the Effect of Viscosity in Electrochemical Experiments Performed in Mixtures of Water with Some Organic Co-Solvents. (en)
skos:prefLabel	The Use of Limiting Currents in Determination of the Effect of Viscosity in Electrochemical Experiments Performed in Mixtures of Water with Some Organic Co-Solvents. The Use of Limiting Currents in Determination of the Effect of Viscosity in Electrochemical Experiments Performed in Mixtures of Water with Some Organic Co-Solvents. (en)
skos:notation	RIV/61388955:_____/03:54030150!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	135;138
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/02/0983), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Ludvík, Jiří Rozbroj, Dan
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	632306
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030150
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	limiting currents; viscosity; polarography (en)
http://linked.open.../riv/klicoveSlovo	polarography viscosity limiting currents
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[81A53B846F03]
http://linked.open...i/riv/nazevZdroje	Journal of Electroanalytical Chemistry
http://linked.open...in/vavai/riv/obor	CG
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Mineralization of organic pollutants by means of novel photocatalysts utilizing solar energy
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	553
http://linked.open...iv/tvurceVysledku	Ludvík, Jiří Celik, H. Zuman, P. Rozbroj, Dan Aleksi.mu., M. Camaione, L.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0022-0728
number of pages	4 (xsd:int)

Faceted Search & Find service v1.16.118 as of Jun 21 2024

Alternative Linked Data Documents: ODE Content Formats:

RDF

ODATA

Microdata

About

OpenLink Virtuoso version 07.20.3240 as of Jun 21 2024, on Linux (x86_64-pc-linux-gnu), Single-Server Edition (126 GB total memory, 58 GB memory in use)
Data on this page belongs to its respective rights holders.
Virtuoso Faceted Browser Copyright © 2009-2024 OpenLink Software