About: ArF Laser -Induced Chemical Vapour Deposition of Polythiene Films from Carbon Disulfide.

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About: ArF Laser -Induced Chemical Vapour Deposition of Polythiene Films from Carbon Disulfide. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Laser photolysis at 193 nm of gaseous carbon disulfide into CS and S in the absence and excess of N2 is controlled by 2 photon-induced depletion of CS2 and affords chemical vapour deposition of (CS)n polymer and Sn. The proposed polymerization mechanism of CS is explained by an intermediacy of C2S2 species. The (CS)n polymer contains S-centred radicals that are stable in air and withstand heating in H2 atmosphere. Its structure is contributed by >C=S, >C=C<, S2C=CS2,, -C-(C=S)-S-), (-S-(C=S)-S- and C-S-S-C configurations whose relative extent depends on irradiation conditions: more C=S bonds (and less C-S bonds) are formed at higher CS2 pressure, in the excess of N2 and with lower laser fluences. The extent of the S2C=CS2 units decreases, and that of >C=C< units increases, upon mild polymer heating. The polymer deposited in the absence of N2 consists of unique 100-200 nm-sized hollow spheres. Laser photolysis at 193 nm of gaseous carbon disulfide into CS and S in the absence and excess of N2 is controlled by 2 photon-induced depletion of CS2 and affords chemical vapour deposition of (CS)n polymer and Sn. The proposed polymerization mechanism of CS is explained by an intermediacy of C2S2 species. The (CS)n polymer contains S-centred radicals that are stable in air and withstand heating in H2 atmosphere. Its structure is contributed by >C=S, >C=C<, S2C=CS2,, -C-(C=S)-S-), (-S-(C=S)-S- and C-S-S-C configurations whose relative extent depends on irradiation conditions: more C=S bonds (and less C-S bonds) are formed at higher CS2 pressure, in the excess of N2 and with lower laser fluences. The extent of the S2C=CS2 units decreases, and that of >C=C< units increases, upon mild polymer heating. The polymer deposited in the absence of N2 consists of unique 100-200 nm-sized hollow spheres. (en)
Title	ArF Laser -Induced Chemical Vapour Deposition of Polythiene Films from Carbon Disulfide. ArF Laser -Induced Chemical Vapour Deposition of Polythiene Films from Carbon Disulfide. (en)
skos:prefLabel	ArF Laser -Induced Chemical Vapour Deposition of Polythiene Films from Carbon Disulfide. ArF Laser -Induced Chemical Vapour Deposition of Polythiene Films from Carbon Disulfide. (en)
skos:notation	RIV/61388955:_____/03:54030128!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	9793;9801
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(ME 612), Z(AV0Z1010914), Z(AV0Z4032918), Z(AV0Z4040901), Z(AV0Z4072921)
http://linked.open...iv/cisloPeriodika	36
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Bastl, Zdeněk
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	599073
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030128
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	laser photolysis; ArF; chemical vapour deposition (en)
http://linked.open.../riv/klicoveSlovo	chemical vapour deposition laser photolysis ArF
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[3DF601A6C99B]
http://linked.open...i/riv/nazevZdroje	Journal of Physical Chemistry. B
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	7 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	http://linked.opendata.cz/resource/domain/vavai/projekt/ME%20612
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	107
http://linked.open...iv/tvurceVysledku	Pola, Josef Tomovska, R. Šubrt, Jan Plzák, Zbyněk Vorlíček, Vladimír Bastl, Zdeněk Vacek, Karel
http://linked.open...n/vavai/riv/zamer	Synthesis and structure of novel (inorganic) compounds, clusters and composites; mechanisms of conversion and transfer in systems involving inorganic substance Experimentální a teoretický výzkum kondenzovaných systémů s význačnými fyzikálními vlastnostmi Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů Theoretical fundamentals of chemical processes: equilibrium and dynamic behavior of multiphase reacting systems
issn	1089-5647
number of pages	9 (xsd:int)

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