About: A SIFT Study of the Reactions of H3O+, NO+ and O2+ with Hydrogen Peroxide and Peroxyacetic Acid.

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About: A SIFT Study of the Reactions of H3O+, NO+ and O2+ with Hydrogen Peroxide and Peroxyacetic Acid. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	We have carried out a selected ion flow tube, SIFT, study of the reactions of H3O+, NO+ and O2+ ions with hydrogen peroxide, H2O2, in the presence of excess water vapour and peroxyacetic acid, CH3C(O)OOH, in the presence of comparable concentrations of acetic acid, CH3COOH. This study was initiated to investigate if these peroxides could be analysed in humid air using selected ion flow tube mass spectrometry, SIFT-MS, using the above precursor ions. Rate coefficients and product ions have been determined for the NO+ and O2+ reactions with H2O2 molecules (H3O+ ions do not react at a measurable rate with H2O2 molecules) and for the rapid reactions of H3O+, NO+ and O2+ with CH3C(O)OOH molecules. It turns out that both H3O+ and O2+ ions are unsuitable for SIFT-MS analyses of these peroxides, either because of low reactivity and/or the production of common product ions for their reactions with H2O and CH3COOH molecules. We have carried out a selected ion flow tube, SIFT, study of the reactions of H3O+, NO+ and O2+ ions with hydrogen peroxide, H2O2, in the presence of excess water vapour and peroxyacetic acid, CH3C(O)OOH, in the presence of comparable concentrations of acetic acid, CH3COOH. This study was initiated to investigate if these peroxides could be analysed in humid air using selected ion flow tube mass spectrometry, SIFT-MS, using the above precursor ions. Rate coefficients and product ions have been determined for the NO+ and O2+ reactions with H2O2 molecules (H3O+ ions do not react at a measurable rate with H2O2 molecules) and for the rapid reactions of H3O+, NO+ and O2+ with CH3C(O)OOH molecules. It turns out that both H3O+ and O2+ ions are unsuitable for SIFT-MS analyses of these peroxides, either because of low reactivity and/or the production of common product ions for their reactions with H2O and CH3COOH molecules. (en)
Title	A SIFT Study of the Reactions of H3O+, NO+ and O2+ with Hydrogen Peroxide and Peroxyacetic Acid. A SIFT Study of the Reactions of H3O+, NO+ and O2+ with Hydrogen Peroxide and Peroxyacetic Acid. (en)
skos:prefLabel	A SIFT Study of the Reactions of H3O+, NO+ and O2+ with Hydrogen Peroxide and Peroxyacetic Acid. A SIFT Study of the Reactions of H3O+, NO+ and O2+ with Hydrogen Peroxide and Peroxyacetic Acid. (en)
skos:notation	RIV/61388955:_____/03:54030121!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	269;283
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA202/03/0827), P(GA203/02/0737), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Španěl, Patrik
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	597138
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030121
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	SIFT; hydrogen peroxide; peroxyacetic acid (en)
http://linked.open.../riv/klicoveSlovo	SIFT hydrogen peroxide peroxyacetic acid
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[1EC00F8BF594]
http://linked.open...i/riv/nazevZdroje	International Journal of Mass Spectrometry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	1 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Mass spectrometric and theoretical characterization of transient molecules A study of elementary processes in low-temperature and technologically oriented plasmas and the development of relevant diagnostic methods
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	228
http://linked.open...iv/tvurceVysledku	Smith, D. Španěl, Patrik Wang, T. Diskin, A. M.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	1387-3806
number of pages	15 (xsd:int)

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