About: The Synthesis of (.eta.5-cyclopentadienyl)Titanium(IV) Alkoxides by Alcoholysis of the Ti- .pí.-Ligand Bond in Permethyl .eta.3:.eta.4-Allyldiene-(.eta.5-cyclopentadienyl)Titanium(II).

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About: The Synthesis of (.eta.5-cyclopentadienyl)Titanium(IV) Alkoxides by Alcoholysis of the Ti- .pí.-Ligand Bond in Permethyl .eta.3:.eta.4-Allyldiene-(.eta.5-cyclopentadienyl)Titanium(II). Goto Sponge NotDistinct Permalink

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Attributes	Values
rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	The .eta.3:.eta.4-allyldiene-(.eta.5-cyclopentadienyl)titanium(II) complex [Ti(.eta.5-C5Me5) {.eta3:.eta.4-C5Me3(CH2)2}] (I) reacts with three molar equivalents of substituted propargylic alcohols FcC=CCMe2(OH) (2a) and PhC=CCH2OH (2b) at elevated temperature to give (.eta.5-pentamethylcyclopentadienyl)titanium(IV) alkoxides [Ti(.eta.5-C5Me5)(FcC=CCMe2-kO)3] (3a) and [Ti(.eta.5-C5Me5)(PhC=CCH2O-kO)3] (3b), respectively. The crystal structure of 3a has been determined by single-crystal X-ray diffraction. The .eta.3:.eta.4-allyldiene-(.eta.5-cyclopentadienyl)titanium(II) complex [Ti(.eta.5-C5Me5) {.eta3:.eta.4-C5Me3(CH2)2}] (I) reacts with three molar equivalents of substituted propargylic alcohols FcC=CCMe2(OH) (2a) and PhC=CCH2OH (2b) at elevated temperature to give (.eta.5-pentamethylcyclopentadienyl)titanium(IV) alkoxides [Ti(.eta.5-C5Me5)(FcC=CCMe2-kO)3] (3a) and [Ti(.eta.5-C5Me5)(PhC=CCH2O-kO)3] (3b), respectively. The crystal structure of 3a has been determined by single-crystal X-ray diffraction. (en)
Title	The Synthesis of (.eta.5-cyclopentadienyl)Titanium(IV) Alkoxides by Alcoholysis of the Ti- .pí.-Ligand Bond in Permethyl .eta.3:.eta.4-Allyldiene-(.eta.5-cyclopentadienyl)Titanium(II). The Synthesis of (.eta.5-cyclopentadienyl)Titanium(IV) Alkoxides by Alcoholysis of the Ti- .pí.-Ligand Bond in Permethyl .eta.3:.eta.4-Allyldiene-(.eta.5-cyclopentadienyl)Titanium(II). (en)
skos:prefLabel	The Synthesis of (.eta.5-cyclopentadienyl)Titanium(IV) Alkoxides by Alcoholysis of the Ti- .pí.-Ligand Bond in Permethyl .eta.3:.eta.4-Allyldiene-(.eta.5-cyclopentadienyl)Titanium(II). The Synthesis of (.eta.5-cyclopentadienyl)Titanium(IV) Alkoxides by Alcoholysis of the Ti- .pí.-Ligand Bond in Permethyl .eta.3:.eta.4-Allyldiene-(.eta.5-cyclopentadienyl)Titanium(II). (en)
skos:notation	RIV/61388955:_____/03:54030092!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany	974;977
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/99/M037), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	N/A
http://linked.open...vai/riv/dodaniDat	2004
http://linked.open...aciTvurceVysledku	Mach, Karel Kubišta, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	630048
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/03:54030092
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	titanium; cyclopentadienyl; ferrocene (en)
http://linked.open.../riv/klicoveSlovo	ferrocene cyclopentadienyl titanium
http://linked.open...odStatuVydavatele	NL - Nizozemsko
http://linked.open...ontrolniKodProRIV	[D5F878591A37]
http://linked.open...i/riv/nazevZdroje	Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	5 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Centre of molecular and crystal structures
http://linked.open...UplatneniVysledku	2003
http://linked.open...v/svazekPeriodika	6
http://linked.open...iv/tvurceVysledku	Císařová, I. Mach, Karel Štěpnička, P. Kubišta, Jiří Trojan, L.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	1387-7003
number of pages	4 (xsd:int)

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