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  • Adsorption of L - .alfa.-lecithin (dipalmitoyl) at the water|1,2-dichloroethane interface has been studied by cyclic voltammetry. It has been found that the voltammetric peak in acidic medium corresponds to the desorption of the protonated form of lecithin. Its surface concentration is controlled by a surface chemical reaction of the zwitter-ionic form of adsorbed lecithin with hydroxonium ion. The whole process is complemented by the potential dependent adsorption/desorption equilibrium of the protonated form of lecithin. Its concentration in the organic phase is affected by the acid-base equilibrium.
  • Adsorption of L - .alfa.-lecithin (dipalmitoyl) at the water|1,2-dichloroethane interface has been studied by cyclic voltammetry. It has been found that the voltammetric peak in acidic medium corresponds to the desorption of the protonated form of lecithin. Its surface concentration is controlled by a surface chemical reaction of the zwitter-ionic form of adsorbed lecithin with hydroxonium ion. The whole process is complemented by the potential dependent adsorption/desorption equilibrium of the protonated form of lecithin. Its concentration in the organic phase is affected by the acid-base equilibrium. (en)
Title
  • Mechanism of Lecithin Adsorption at a Liquid/Liquid Interface.
  • Mechanism of Lecithin Adsorption at a Liquid/Liquid Interface. (en)
skos:prefLabel
  • Mechanism of Lecithin Adsorption at a Liquid/Liquid Interface.
  • Mechanism of Lecithin Adsorption at a Liquid/Liquid Interface. (en)
skos:notation
  • RIV/61388955:_____/03:54030055!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany
  • 4573;4578
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/00/0636), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • 19
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 614704
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/03:54030055
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • adsorption; mechanism of lecithin; liquid/liquid interface (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [562C7BEA2CF0]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry. B
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 107
http://linked.open...iv/tvurceVysledku
  • Mareček, Vladimír
  • Jänchenová, Hana
  • Lhotský, Alexandr
http://linked.open...n/vavai/riv/zamer
issn
  • 1089-5647
number of pages
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