About: Ti(C5Me3RSiMe2NBut)Cl2] (R = alkyl or aryl) complexes as catalysts for ethylene polymerization.     Goto   Sponge   NotDistinct   Permalink

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Description
  • Ti(C5Me3RSiMe2NBut)Cl2] (R = alkyl or aryl) complexes in combination with methylaluminoxane were found to be highly efficient catalysts towards ethylene polymerization. The species with aromatic R groups display higher activity than those with aliphatic ones. This tendency could not be correlated with the electronic properties of the complexes that were evaluated by cyclic voltammetry. The polyethylenes obtained in the catalytic processes were characteized by 1H NMR and DSC.
  • Ti(C5Me3RSiMe2NBut)Cl2] (R = alkyl or aryl) complexes in combination with methylaluminoxane were found to be highly efficient catalysts towards ethylene polymerization. The species with aromatic R groups display higher activity than those with aliphatic ones. This tendency could not be correlated with the electronic properties of the complexes that were evaluated by cyclic voltammetry. The polyethylenes obtained in the catalytic processes were characteized by 1H NMR and DSC. (en)
Title
  • Ti(C5Me3RSiMe2NBut)Cl2] (R = alkyl or aryl) complexes as catalysts for ethylene polymerization.
  • Ti(C5Me3RSiMe2NBut)Cl2] (R = alkyl or aryl) complexes as catalysts for ethylene polymerization. (en)
skos:prefLabel
  • Ti(C5Me3RSiMe2NBut)Cl2] (R = alkyl or aryl) complexes as catalysts for ethylene polymerization.
  • Ti(C5Me3RSiMe2NBut)Cl2] (R = alkyl or aryl) complexes as catalysts for ethylene polymerization. (en)
skos:notation
  • RIV/61388955:_____/03:54030012!RIV/2004/AV0/A54004/N
http://linked.open.../vavai/riv/strany
  • 331;334
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(IBS4040017), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • N/A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 631020
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/03:54030012
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • catalysis; polymerization; ethylene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • NL - Nizozemsko
http://linked.open...ontrolniKodProRIV
  • [3B4D39DA2A04]
http://linked.open...i/riv/nazevZdroje
  • Inorganic Chemistry Communications
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 6
http://linked.open...iv/tvurceVysledku
  • Mach, Karel
  • Pombeiro, A. J. L.
  • Carvalho, M. F. N.
  • Dias, A. R.
  • Mano, J. F.
  • Margues, M. M.
  • Soares, A. M.
http://linked.open...n/vavai/riv/zamer
issn
  • 1387-7003
number of pages
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