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rdf:type
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Description
| - Die komplexe [(mmb)Re(CO)3Cl] [(mtb)Re(CO)3Cl], [mmb)OsCl(Cym)](PF6) und [mtb)OsCl(Cym)](PF6) mit Cym = p-Cymol, mmb = 1-methyl-(2-methylthiomethyl)-1H-benzimidazol and mtb = 1-methyl-(2-tert-butylthiomethyl)-1H-benzimidazol wurden dargestellt und mit ausnahme der letztgenannten verbindung strukturell charakterisiert. Anodische eineelektronen-oxidation EPR Rhenium(II) währen die osmium(III) - spezies [(mmb)OsCl(cym)]2+ über EPR und UV/VIS spektroelektrochemie.
- The complexes [(mmb)Re(CO)(3)Cl], [(mtb,)Re(CO)(3)Cl], [(mmb)OsCl(Cym)](PF6) and [(Cym)OsCl(mtb)](PF6) where Cym = p-cymene, mmb = 1-methyl-(2-methylthiomethyl)-1H-benzimidazole and mtb = 1-methyl(2-tert-butylthiomethyl)-1H-benzimidazole were synthesized and, except for the latter, structurally characterized. In comparison with other late transition metal compounds of these N-S chelate ligands the rhenium(l) systems exhibit a balanced coordination to both N and S donor atoms. Anodic one-electron oxidation produces EPR-silent rhenium(II) states whereas the osmium(111) species [(mmb)OsCl(Cym)](2+) could be identified via EPR and UV/VlS spectroelectrochemistry. (en)
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Title
| - Metallorganische 5d6-Übergangsmetallkomplexe von zwei 1-Methyl-(2-alkylthiomethyl)-1H-benzimidazol-Liganden:Strukturen und elektrochemische Oxidation.
- Organometallic 5d(6) transition metal complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazole ligands: Structures and electrochemical oxidation. (en)
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skos:prefLabel
| - Metallorganische 5d6-Übergangsmetallkomplexe von zwei 1-Methyl-(2-alkylthiomethyl)-1H-benzimidazol-Liganden:Strukturen und elektrochemische Oxidation.
- Organometallic 5d(6) transition metal complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazole ligands: Structures and electrochemical oxidation. (en)
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skos:notation
| - RIV/61388955:_____/02:54020161!RIV/2003/AV0/A54003/N
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http://linked.open.../vavai/riv/strany
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http://linked.open...avai/riv/aktivita
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http://linked.open...avai/riv/aktivity
| - P(OC D14.20), Z(AV0Z4040901)
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http://linked.open...iv/cisloPeriodika
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http://linked.open...vai/riv/dodaniDat
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http://linked.open...aciTvurceVysledku
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http://linked.open.../riv/druhVysledku
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http://linked.open...iv/duvernostUdaju
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http://linked.open...titaPredkladatele
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http://linked.open...dnocenehoVysledku
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http://linked.open...ai/riv/idVysledku
| - RIV/61388955:_____/02:54020161
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http://linked.open...riv/jazykVysledku
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http://linked.open.../riv/klicovaSlova
| - benzimidazole ligands; crystal structures; osmium (en)
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http://linked.open.../riv/klicoveSlovo
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http://linked.open...odStatuVydavatele
| - DE - Spolková republika Německo
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http://linked.open...ontrolniKodProRIV
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http://linked.open...i/riv/nazevZdroje
| - Zeitschrift für Anorganische und Allgemeine Chemie
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http://linked.open...in/vavai/riv/obor
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http://linked.open...ichTvurcuVysledku
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http://linked.open...cetTvurcuVysledku
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http://linked.open...ocetUcastnikuAkce
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http://linked.open...nichUcastnikuAkce
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http://linked.open...vavai/riv/projekt
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http://linked.open...UplatneniVysledku
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http://linked.open...v/svazekPeriodika
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http://linked.open...iv/tvurceVysledku
| - Fiedler, Jan
- Kaim, W.
- Wanner, M.
- Knödler, A.
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http://linked.open...n/vavai/riv/zamer
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issn
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number of pages
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