About: Collisions of Slow Polyatomic Ions with Surfaces: Dissociation and Chemical Reactions of CD5+, CD4+, CD3+ and Their Isotopic Variants on Room-Temperature and Heated Carbon Surfaces.     Goto   Sponge   NotDistinct   Permalink

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Description
  • Interaction of small hydrocarbon ions, CD3+, CD4+, CD5+, and their isotopic variants CHn+ and (CHn+)-C-13 (n = 3, 4, 5), with room-temperature and heated carbon (highly oriented pyrolytic graphite, HOPG) surfaces was investigated over the collision energy range 16-52 eV. Mass spectra, translational energy distributions, and angular distributions of product ions were determined. Collisions with room-temperature surfaces showed both surface-induced dissociation of the projectiles and chemical reactions with the surface material. All projectiles showed formation,of C2X3+ (X = H, D) in interaction of the projectiles with terminal CH3-groups of surface-adsorbed hydrocarbons and a small amount of C-3 product ions, and collisions of CD4+ led, in addition, to CD4H+ by H-atom transfer from surface hydrocarbons. The surface collisions were inelastic with 41-55 of incident energy in product-ion translation (incident angle 60degrees with respect to the surface normal).
  • Interaction of small hydrocarbon ions, CD3+, CD4+, CD5+, and their isotopic variants CHn+ and (CHn+)-C-13 (n = 3, 4, 5), with room-temperature and heated carbon (highly oriented pyrolytic graphite, HOPG) surfaces was investigated over the collision energy range 16-52 eV. Mass spectra, translational energy distributions, and angular distributions of product ions were determined. Collisions with room-temperature surfaces showed both surface-induced dissociation of the projectiles and chemical reactions with the surface material. All projectiles showed formation,of C2X3+ (X = H, D) in interaction of the projectiles with terminal CH3-groups of surface-adsorbed hydrocarbons and a small amount of C-3 product ions, and collisions of CD4+ led, in addition, to CD4H+ by H-atom transfer from surface hydrocarbons. The surface collisions were inelastic with 41-55 of incident energy in product-ion translation (incident angle 60degrees with respect to the surface normal). (en)
Title
  • Collisions of Slow Polyatomic Ions with Surfaces: Dissociation and Chemical Reactions of CD5+, CD4+, CD3+ and Their Isotopic Variants on Room-Temperature and Heated Carbon Surfaces.
  • Collisions of Slow Polyatomic Ions with Surfaces: Dissociation and Chemical Reactions of CD5+, CD4+, CD3+ and Their Isotopic Variants on Room-Temperature and Heated Carbon Surfaces. (en)
skos:prefLabel
  • Collisions of Slow Polyatomic Ions with Surfaces: Dissociation and Chemical Reactions of CD5+, CD4+, CD3+ and Their Isotopic Variants on Room-Temperature and Heated Carbon Surfaces.
  • Collisions of Slow Polyatomic Ions with Surfaces: Dissociation and Chemical Reactions of CD5+, CD4+, CD3+ and Their Isotopic Variants on Room-Temperature and Heated Carbon Surfaces. (en)
skos:notation
  • RIV/61388955:_____/02:54020144!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany
  • 8293;8301
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • P(GA203/00/0632), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika
  • N/A
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
http://linked.open.../riv/druhVysledku
http://linked.open...iv/duvernostUdaju
http://linked.open...titaPredkladatele
http://linked.open...dnocenehoVysledku
  • 641138
http://linked.open...ai/riv/idVysledku
  • RIV/61388955:_____/02:54020144
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • liquid surface; - scattering; - energies (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • US - Spojené státy americké
http://linked.open...ontrolniKodProRIV
  • [CF2B4D6A94B3]
http://linked.open...i/riv/nazevZdroje
  • Journal of Physical Chemistry. B
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
http://linked.open...cetTvurcuVysledku
http://linked.open...ocetUcastnikuAkce
http://linked.open...nichUcastnikuAkce
http://linked.open...vavai/riv/projekt
http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 106
http://linked.open...iv/tvurceVysledku
  • Žabka, Ján
  • Herman, Zdeněk
  • Roithová, Jana
  • Dolejšek, Zdeněk
http://linked.open...n/vavai/riv/zamer
issn
  • 1089-5647
number of pages
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