About: Inhibition of Ion Transfer Reactions by Compact Layers at a Liquid/liquid Interface.

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About: Inhibition of Ion Transfer Reactions by Compact Layers at a Liquid/liquid Interface. Goto Sponge NotDistinct Permalink

An Entity of Type : http://linked.opendata.cz/ontology/domain/vavai/Vysledek, within Data Space : linked.opendata.cz associated with source document(s)

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	It is demonstrated that adsorbed layers of surface active compounds dissolved in organic phase can be stabilized by a chemical reaction resulting in oxidation of adsorbed monomers by a redox couple dissolved in water. Oxidation of the adsorbed monomer leads to the formation of a compact polymer layer. This formation can be monitored by surface tension measurement and by cyclic voltammetry in the presence of transferable ions. In contrast to a simple adsorbed layer, interfacial tension in the presence of a polymer layer becomes almost independent of the applied potential and the formed polymer layer strongly inhibits ion transfer reactions. It is demonstrated that adsorbed layers of surface active compounds dissolved in organic phase can be stabilized by a chemical reaction resulting in oxidation of adsorbed monomers by a redox couple dissolved in water. Oxidation of the adsorbed monomer leads to the formation of a compact polymer layer. This formation can be monitored by surface tension measurement and by cyclic voltammetry in the presence of transferable ions. In contrast to a simple adsorbed layer, interfacial tension in the presence of a polymer layer becomes almost independent of the applied potential and the formed polymer layer strongly inhibits ion transfer reactions. (en)
Title	Inhibition of Ion Transfer Reactions by Compact Layers at a Liquid/liquid Interface. Inhibition of Ion Transfer Reactions by Compact Layers at a Liquid/liquid Interface. (en)
skos:prefLabel	Inhibition of Ion Transfer Reactions by Compact Layers at a Liquid/liquid Interface. Inhibition of Ion Transfer Reactions by Compact Layers at a Liquid/liquid Interface. (en)
skos:notation	RIV/61388955:_____/02:54020005!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	325;327
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/00/0636), Z(AV0Z4040901)
http://linked.open...iv/cisloPeriodika	Supplement
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Lhotský, Alexandr Jänchenová, Hana Mareček, Vladimír
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	649166
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/02:54020005
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	immiscible electrolytes; - compact layer; - polymerisation (en)
http://linked.open.../riv/klicoveSlovo	- compact layer - polymerisation immiscible electrolytes
http://linked.open...odStatuVydavatele	JP - Japonsko
http://linked.open...ontrolniKodProRIV	[B0156C46F0C4]
http://linked.open...i/riv/nazevZdroje	Analytical Sciences
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	6 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Formation and investigation of compact layers at liquid/liquid interfaces
http://linked.open...UplatneniVysledku	2002
http://linked.open...v/svazekPeriodika	17
http://linked.open...iv/tvurceVysledku	Mareček, Vladimír Budka, J. Maeda, K. Jänchenová, Hana Lhotský, Alexandr Stibor, I.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů
issn	0910-6340
number of pages	3 (xsd:int)

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