About: Syntheses and Structures of Doubly Tucked-in Titanocene Complexes with Tetramethyl(aryl)cyclopentadienyl Ligands.

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About: Syntheses and Structures of Doubly Tucked-in Titanocene Complexes with Tetramethyl(aryl)cyclopentadienyl Ligands. Goto Sponge NotDistinct Permalink

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
Description	Titanocene-bis(trimethylsilyl)ethyne complexes [Ti(.eta.5-C5Me4R)2(.eta.2-Me3SiC.ident.CSiMe3)], where R=benzyl, phenyl and p-fluorophenyl thermolyze at 150-160.mult.C to give products of double C-H activation e.g. [Ti(.eta.5-C5Me4Ph){.eta.3:.eta.4-C5Me2Ph(CH2)2}]. In the presence of 2,2,7,7-tetramethylocta-3,5-diyne(TMOD), the thermolysis affords analogous doubly tucked-in-compounds bearing one .eta.3:.eta.4-allyldiene and one .eta.5-C5Me4R ligand having TMOD attached to two carbon atoms vicinal to substituent R. Titanocene-bis(trimethylsilyl)ethyne complexes [Ti(.eta.5-C5Me4R)2(.eta.2-Me3SiC.ident.CSiMe3)], where R=benzyl, phenyl and p-fluorophenyl thermolyze at 150-160.mult.C to give products of double C-H activation e.g. [Ti(.eta.5-C5Me4Ph){.eta.3:.eta.4-C5Me2Ph(CH2)2}]. In the presence of 2,2,7,7-tetramethylocta-3,5-diyne(TMOD), the thermolysis affords analogous doubly tucked-in-compounds bearing one .eta.3:.eta.4-allyldiene and one .eta.5-C5Me4R ligand having TMOD attached to two carbon atoms vicinal to substituent R. (en)
Title	Syntheses and Structures of Doubly Tucked-in Titanocene Complexes with Tetramethyl(aryl)cyclopentadienyl Ligands. Syntheses and Structures of Doubly Tucked-in Titanocene Complexes with Tetramethyl(aryl)cyclopentadienyl Ligands. (en)
skos:prefLabel	Syntheses and Structures of Doubly Tucked-in Titanocene Complexes with Tetramethyl(aryl)cyclopentadienyl Ligands. Syntheses and Structures of Doubly Tucked-in Titanocene Complexes with Tetramethyl(aryl)cyclopentadienyl Ligands. (en)
skos:notation	RIV/61388955:_____/01:54010031!RIV/2003/AV0/A54003/N
http://linked.open.../vavai/riv/strany	39;50
http://linked.open...avai/riv/aktivita	P Z
http://linked.open...avai/riv/aktivity	P(GA203/99/0067), P(GA203/99/0846), P(IBS4040017), Z(AV0Z4040901), Z(MSM 113100001)
http://linked.open...iv/cisloPeriodika	1
http://linked.open...vai/riv/dodaniDat	2003
http://linked.open...aciTvurceVysledku	Horáček, Michal Mach, Karel Kubišta, Jiří
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Ústav fyzikální chemie J. Heyrovského AV ČR, v.v.i.
http://linked.open...dnocenehoVysledku	698087
http://linked.open...ai/riv/idVysledku	RIV/61388955:_____/01:54010031
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	bis(trimethylsilyl)ethyne complexes; - C-H activation; - crystal structure (en)
http://linked.open.../riv/klicoveSlovo	- crystal structure - C-H activation bis(trimethylsilyl)ethyne complexes
http://linked.open...odStatuVydavatele	CH - Švýcarská konfederace
http://linked.open...ontrolniKodProRIV	[9515B5AA8881]
http://linked.open...i/riv/nazevZdroje	Journal of Organometallic Chemistry
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	8 (xsd:int)
http://linked.open...ocetUcastnikuAkce	0 (xsd:int)
http://linked.open...nichUcastnikuAkce	0 (xsd:int)
http://linked.open...vavai/riv/projekt	Lease of crystallographic databases Titanocene-acetylene chemistry - application in organometallic synthesis and catalysis Metallocene catalysts anchored on mesoporous support of the MCM-41 type
http://linked.open...UplatneniVysledku	2001
http://linked.open...v/svazekPeriodika	620
http://linked.open...iv/tvurceVysledku	Mach, Karel Štěpnička, P. Gyepes, R. Horáček, Michal Kubišta, Jiří Tišlerová, I. Thewalt, U. Kupfer, V.
http://linked.open...n/vavai/riv/zamer	Objasňování zákonitostí vztahů struktury a vlastností - zejména dynamiky a chemické reaktivity - látek a molekulárních systémů http://linked.opendata.cz/resource/domain/vavai/zamer/MSM%20113100001
issn	0022-328X
number of pages	12 (xsd:int)

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