About: Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes     Goto   Sponge   NotDistinct   Permalink

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Description
  • The meta-iodo derivative, fixed in the cone conformation, enables the gram-scale preparation of a meta-bridged calix[4]arene. This intermediate, possessing a fluorene moiety within the macrocyclic skeleton, can be regioselectively alkylated on the corresponding methylene bridge to form a unique substitution pattern in classical calixarene chemistry.
  • The meta-iodo derivative, fixed in the cone conformation, enables the gram-scale preparation of a meta-bridged calix[4]arene. This intermediate, possessing a fluorene moiety within the macrocyclic skeleton, can be regioselectively alkylated on the corresponding methylene bridge to form a unique substitution pattern in classical calixarene chemistry. (en)
Title
  • Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes
  • Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes (en)
skos:prefLabel
  • Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes
  • Regioselective alkylation of a methylene group via meta-bridging of calix[4]arenes (en)
skos:notation
  • RIV/60461373:22810/14:43898111!RIV15-MSM-22810___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • S
http://linked.open...iv/cisloPeriodika
  • 70
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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  • 41868
http://linked.open...ai/riv/idVysledku
  • RIV/60461373:22810/14:43898111
http://linked.open...riv/jazykVysledku
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  • cyclization; conformation; clinical chemistry; catalyst; article; alkylation; unclassified drug; fluorene; carbene; calix[4]arene; calixarene (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [78B6F81EFF4A]
http://linked.open...i/riv/nazevZdroje
  • Chemical Communications
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  • 50
http://linked.open...iv/tvurceVysledku
  • Slavík, Petr
  • Dvořáková, Hana
  • Lhoták, Pavel
  • Eigner, Václav
http://linked.open...ain/vavai/riv/wos
  • 000340707600028
issn
  • 1359-7345
number of pages
http://bibframe.org/vocab/doi
  • 10.1039/c4cc04356a
http://localhost/t...ganizacniJednotka
  • 22810
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