About: Local kinetics and thermodynamics of rapid electrochemical reactions

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://journals.aps.org/pre/abstract/10.1103/PhysRevE.89.042403
Description	We introduce and discuss a local kinetic mechanism for an n-electron electrochemical reaction at the interface formed by an electrode and diluted electrolyte. We show that the suggested mechanism is in agreement with the Nernst equation in the thermal equilibrium. We also qualitatively characterize the structure of a flat electrodediluted electrolyte boundary in the meaning of the spatial distribution of electrochemical reactants and electric potential. As the suggested kinetic mechanism is not limited by the duration of relaxation processes in electric double layers, it is suitable for the understanding and simulation of fast transient processes that appear in modern applications such as nanocolloid dielectrophoresis, AC electrospray, AC electroosmosis, or nanopore biosensing. We introduce and discuss a local kinetic mechanism for an n-electron electrochemical reaction at the interface formed by an electrode and diluted electrolyte. We show that the suggested mechanism is in agreement with the Nernst equation in the thermal equilibrium. We also qualitatively characterize the structure of a flat electrodediluted electrolyte boundary in the meaning of the spatial distribution of electrochemical reactants and electric potential. As the suggested kinetic mechanism is not limited by the duration of relaxation processes in electric double layers, it is suitable for the understanding and simulation of fast transient processes that appear in modern applications such as nanocolloid dielectrophoresis, AC electrospray, AC electroosmosis, or nanopore biosensing. (en)
Title	Local kinetics and thermodynamics of rapid electrochemical reactions Local kinetics and thermodynamics of rapid electrochemical reactions (en)
skos:prefLabel	Local kinetics and thermodynamics of rapid electrochemical reactions Local kinetics and thermodynamics of rapid electrochemical reactions (en)
skos:notation	RIV/60461373:22340/14:43897820!RIV15-GA0-22340___
http://linked.open...avai/riv/aktivita	P
http://linked.open...avai/riv/aktivity	P(GA14-01781S)
http://linked.open...iv/cisloPeriodika	4
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Přibyl, Michal Šnita, Dalimil
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	26454
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/14:43897820
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	electrochemical reactions; thermodynamics; kinetics; Local (en)
http://linked.open.../riv/klicoveSlovo	electrochemical reactions kinetics thermodynamics Local
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[4BDDC305636F]
http://linked.open...i/riv/nazevZdroje	Physical Review E
http://linked.open...in/vavai/riv/obor	BK
http://linked.open...ichTvurcuVysledku	2 (xsd:int)
http://linked.open...cetTvurcuVysledku	2 (xsd:int)
http://linked.open...vavai/riv/projekt	Investigation on fluid mechanics in smart microsystems driven by electric fields
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	89
http://linked.open...iv/tvurceVysledku	Šnita, Dalimil Přibyl, Michal
http://linked.open...ain/vavai/riv/wos	000333983100004
issn	1539-3755
number of pages	4 (xsd:int)
http://bibframe.org/vocab/doi	10.1103/PhysRevE.89.042403
http://localhost/t...ganizacniJednotka	22340

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