About: Liquid-Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol plus Perfluorocarbon plus Water or Methanol at 298.15 K

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rdf:type	skos:Concept http://linked.opendata.cz/ontology/domain/vavai/Vysledek
rdfs:seeAlso	http://pubs.acs.org/doi/abs/10.1021/je500455u
Description	Liquid-liquid equilibrium data for ternary systems hexafluoroisopropanol perfluorocarbon (namely perfluoro(n-hexane) or perfluoro(methylcyclohexane)) water or methanol were determined at 298.15 K. Water, methanol and other polar solvents exhibit very low miscibility with perfluorocarbons. In contrast, hexafluoroisopropanol is fully miscible with water, methanol and perfluorocarbons. Consequently, the determined ternary liquid-liquid equilibrium diagrams possess only one heterogeneous binary subsystem. They are of the type 1. Due to specific properties of perfluorocarbons a special procedure for determination of the liquid-liquid equilibrium in the studied systems was developed. The ternary liquid-liquid equilibrium diagrams were found to be almost identical for perfluoro(n-hexane) and perfluoro(methylcyclohexane) showing that the structure of perfluorocarbon component has minimal influence on the miscibility behavior. Liquid-liquid equilibrium data for ternary systems hexafluoroisopropanol perfluorocarbon (namely perfluoro(n-hexane) or perfluoro(methylcyclohexane)) water or methanol were determined at 298.15 K. Water, methanol and other polar solvents exhibit very low miscibility with perfluorocarbons. In contrast, hexafluoroisopropanol is fully miscible with water, methanol and perfluorocarbons. Consequently, the determined ternary liquid-liquid equilibrium diagrams possess only one heterogeneous binary subsystem. They are of the type 1. Due to specific properties of perfluorocarbons a special procedure for determination of the liquid-liquid equilibrium in the studied systems was developed. The ternary liquid-liquid equilibrium diagrams were found to be almost identical for perfluoro(n-hexane) and perfluoro(methylcyclohexane) showing that the structure of perfluorocarbon component has minimal influence on the miscibility behavior. (en)
Title	Liquid-Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol plus Perfluorocarbon plus Water or Methanol at 298.15 K Liquid-Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol plus Perfluorocarbon plus Water or Methanol at 298.15 K (en)
skos:prefLabel	Liquid-Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol plus Perfluorocarbon plus Water or Methanol at 298.15 K Liquid-Liquid Equilibria in Ternary Systems of Hexafluoroisopropanol plus Perfluorocarbon plus Water or Methanol at 298.15 K (en)
skos:notation	RIV/60461373:22340/14:43897761!RIV15-MSM-22340___
http://linked.open...avai/riv/aktivita	I S
http://linked.open...avai/riv/aktivity	I, S
http://linked.open...iv/cisloPeriodika	11
http://linked.open...vai/riv/dodaniDat	2015
http://linked.open...aciTvurceVysledku	Řehák, Karel Morávek, Pavel Strejc, Martin
http://linked.open.../riv/druhVysledku	J - Článek v odborném periodiku
http://linked.open...iv/duvernostUdaju	S - Úplné a pravdivé údaje nepodléhající ochraně podle zvláštních právních předpisů
http://linked.open...titaPredkladatele	Vysoká škola chemicko-technologická v Praze / Fakulta chemicko-inženýrská
http://linked.open...dnocenehoVysledku	26331
http://linked.open...ai/riv/idVysledku	RIV/60461373:22340/14:43897761
http://linked.open...riv/jazykVysledku	eng - angličtina
http://linked.open.../riv/klicovaSlova	Perfluorocarbons; Water; Hexafluoroisopropanol; Liquid-liquid phase equilibrium (en)
http://linked.open.../riv/klicoveSlovo	Hexafluoroisopropanol Liquid-liquid phase equilibrium Perfluorocarbons Water
http://linked.open...odStatuVydavatele	US - Spojené státy americké
http://linked.open...ontrolniKodProRIV	[43BDAAD0AEA3]
http://linked.open...i/riv/nazevZdroje	Journal of Chemical Engineering Data
http://linked.open...in/vavai/riv/obor	CF
http://linked.open...ichTvurcuVysledku	3 (xsd:int)
http://linked.open...cetTvurcuVysledku	4 (xsd:int)
http://linked.open...UplatneniVysledku	2014
http://linked.open...v/svazekPeriodika	59
http://linked.open...iv/tvurceVysledku	Beier, Petr Řehák, Karel Morávek, Pavel Strejc, Martin
http://linked.open...ain/vavai/riv/wos	000344977600025
issn	0021-9568
number of pages	7 (xsd:int)
http://bibframe.org/vocab/doi	10.1021/je500455u
http://localhost/t...ganizacniJednotka	22340

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