About: Experimental and theoretical investigation of the reactive granulation of sodium carbonate with dodecyl-benzenesulfonic acid     Goto   Sponge   NotDistinct   Permalink

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  • Sodium dodecyl-benzenesulfonate is an industrially important anionic surfactant, used in detergent powders and other cleaning products. It is produced by the neutralisation of dodecyl-benzenesulfonic acid with a liquid or a solid base. In the latter case, called dry neutralisation, the acid simultaneously acts as a granulation binder and the reaction kinetics determine not only the overall conversion but also the properties of the formed granules. In this work, the measurement of the kinetics of dry neutralisation using a laboratory-scale mechanically agitated granulator is described. The volume of evolved CO2, which is a by-product of the reaction, has been recorded as a function of time for several temperatures and agitation rates. A mathematical model of the process has been formulated and used in conjunction with experimental data to calculate the reaction rate as a function of operating parameters.
  • Sodium dodecyl-benzenesulfonate is an industrially important anionic surfactant, used in detergent powders and other cleaning products. It is produced by the neutralisation of dodecyl-benzenesulfonic acid with a liquid or a solid base. In the latter case, called dry neutralisation, the acid simultaneously acts as a granulation binder and the reaction kinetics determine not only the overall conversion but also the properties of the formed granules. In this work, the measurement of the kinetics of dry neutralisation using a laboratory-scale mechanically agitated granulator is described. The volume of evolved CO2, which is a by-product of the reaction, has been recorded as a function of time for several temperatures and agitation rates. A mathematical model of the process has been formulated and used in conjunction with experimental data to calculate the reaction rate as a function of operating parameters. (en)
Title
  • Experimental and theoretical investigation of the reactive granulation of sodium carbonate with dodecyl-benzenesulfonic acid
  • Experimental and theoretical investigation of the reactive granulation of sodium carbonate with dodecyl-benzenesulfonic acid (en)
skos:prefLabel
  • Experimental and theoretical investigation of the reactive granulation of sodium carbonate with dodecyl-benzenesulfonic acid
  • Experimental and theoretical investigation of the reactive granulation of sodium carbonate with dodecyl-benzenesulfonic acid (en)
skos:notation
  • RIV/60461373:22340/13:43895524!RIV14-MSM-22340___
http://linked.open...avai/riv/aktivita
http://linked.open...avai/riv/aktivity
  • S
http://linked.open...iv/cisloPeriodika
  • 4 February 2013
http://linked.open...vai/riv/dodaniDat
http://linked.open...aciTvurceVysledku
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http://linked.open...dnocenehoVysledku
  • 74011
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  • RIV/60461373:22340/13:43895524
http://linked.open...riv/jazykVysledku
http://linked.open.../riv/klicovaSlova
  • Population balance; Mathematical modelling; Detergents; Granulation; Diffusion; Reaction (en)
http://linked.open.../riv/klicoveSlovo
http://linked.open...odStatuVydavatele
  • GB - Spojené království Velké Británie a Severního Irska
http://linked.open...ontrolniKodProRIV
  • [E1BB1E4CB5E5]
http://linked.open...i/riv/nazevZdroje
  • Chemical Engineering Science
http://linked.open...in/vavai/riv/obor
http://linked.open...ichTvurcuVysledku
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http://linked.open...UplatneniVysledku
http://linked.open...v/svazekPeriodika
  • 86
http://linked.open...iv/tvurceVysledku
  • Štěpánek, František
  • Schöngut, Marek
  • Smrčka, David
http://linked.open...ain/vavai/riv/wos
  • 000311431800002
issn
  • 0009-2509
number of pages
http://bibframe.org/vocab/doi
  • 10.1016/j.ces.2012.01.003
http://localhost/t...ganizacniJednotka
  • 22340
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